| Full text | |
| Author(s): |
Brito, J.
[1]
;
Rizzo, L. V.
[2]
;
Herckes, P.
[3]
;
Vasconcellos, P. C.
[4]
;
Caumo, S. E. S.
[4]
;
Fornaro, A.
[5]
;
Ynoue, R. Y.
[5]
;
Artaxo, P.
[1]
;
Andrade, M. F.
[5]
Total Authors: 9
|
| Affiliation: | [1] Univ Sao Paulo, Inst Phys, BR-05508 Sao Paulo - Brazil
[2] Univ Fed Sao Paulo, Dept Earth & Exact Sci, Sao Paulo - Brazil
[3] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ - USA
[4] Univ Sao Paulo, Inst Chem, BR-05508 Sao Paulo - Brazil
[5] Univ Sao Paulo, Inst Astron Geophys & Atmospher Sci, BR-05508 Sao Paulo - Brazil
Total Affiliations: 5
|
| Document type: | Journal article |
| Source: | Atmospheric Chemistry and Physics; v. 13, n. 24, p. 12199-12213, 2013. |
| Web of Science Citations: | 38 |
| Abstract | |
The notable increase in biofuel usage by the road transportation sector in Brazil during recent years has significantly altered the vehicular fuel composition. Consequently, many uncertainties are currently found in particulate matter vehicular emission profiles. In an effort to better characterise the emitted particulate matter, measurements of aerosol physical and chemical properties were undertaken inside two tunnels located in the Sao Paulo Metropolitan Area (SPMA). The tunnels show very distinct fleet profiles: in the Janio Quadros (JQ) tunnel, the vast majority of the circulating fleet are light duty vehicles (LDVs), fuelled on average with the same amount of ethanol as gasoline. In the Rodoanel (RA) tunnel, the particulate emission is dominated by heavy duty vehicles (HDVs) fuelled with diesel (5% biodiesel). In the JQ tunnel, PM2.5 concentration was on average 52 mu gm(-3), with the largest contribution of organic mass (OM, 42 %), followed by elemental carbon (EC, 17 %) and crustal elements (13 %). Sulphate accounted for 7% of PM2.5 and the sum of other trace elements was 10%. In the RA tunnel, PM2.5 was on average 233 mu gm(-3), mostly composed of EC (52 %) and OM (39 %). Sulphate, crustal and the trace elements showed a minor contribution with 5 %, 1 %, and 1 %, respectively. The average OC : EC ratio in the JQ tunnel was 1.59 +/- 0.09, indicating an important contribution of EC despite the high ethanol fraction in the fuel composition. In the RA tunnel, the OC: EC ratio was 0.49 +/- 0.12, consistent with previous measurements of diesel-fuelled HDVs. Besides bulk carbonaceous aerosol measurement, polycyclic aromatic hydrocarbons (PAHs) were quantified. The sum of the PAHs concentration was 56 +/- 5 ngm(-3) and 45 +/- 9 ngm(-3) in the RA and JQ tunnel, respectively. In the JQ tunnel, benzo(a) pyrene (BaP) ranged from 0.9 to 6.7 ngm(-3) (0.02-0. 1 parts per thousand of PM2.5) whereas in the RA tunnel BaP ranged from 0.9 to 4.9 ngm(-3) (0.004-0. 02 parts per thousand of PM2.5), indicating an important relative contribution of LDVs emission to atmospheric BaP. Real-time measurements performed in both tunnels provided aerosol size distributions and optical properties. The average particle count yielded 73 000 cm(-3) in the JQ tunnel and 366 000 cm(-3) in the RA tunnel, with an average diameter of 48 nm in the former and 39 nm in the latter. Aerosol single scattering albedo, calculated from scattering and absorption observations in the JQ tunnel, indicates a value of 0.5 associated with LDVs. Such single scattering albedo is 20-50% higher than observed in previous tunnel studies, possibly as a result of the large biofuel usage. Given the exceedingly high equivalent black carbon loadings in the RA tunnel, real time light absorption measurements were possible only in the JQ tunnel. Nevertheless, using EC measured from the filters, a single scattering albedo of 0.31 for the RA tunnel has been estimated. The results presented here characterise particulate matter emitted from nearly 1 million vehicles fuelled with a considerable amount of biofuel, providing a unique experimental site worldwide. (AU) | |
| FAPESP's process: | 08/58104-8 - Narrowing the uncertainties on aerosol and climate changes in São Paulo State: NUANCES-SPS |
| Grantee: | Maria de Fátima Andrade |
| Support Opportunities: | Research Program on Global Climate Change - Thematic Grants |