| Full text | |
| Author(s): |
Rohwedder, J. J. R.
[1]
;
Pasquini, C.
[1]
;
Fortes, P. R.
[1]
;
Raimundo, Jr., I. M.
[1]
;
Wilk, A.
[2]
;
Mizaikoff, B.
[2]
Total Authors: 6
|
| Affiliation: | [1] Univ Estadual Campinas, Inst Chem, BR-13083970 Campinas, SP - Brazil
[2] Univ Ulm, Inst Analyt & Bioanalyt Chem, D-89081 Ulm - Germany
Total Affiliations: 2
|
| Document type: | Journal article |
| Source: | ANALYST; v. 139, n. 14, p. 3572-3576, 2014. |
| Web of Science Citations: | 24 |
| Abstract | |
A miniaturised gas analyser is described and evaluated based on the use of a substrate-integrated hollow waveguide (iHWG) coupled to a microsized near-infrared spectrophotometer comprising a linear variable filter and an array of InGaAs detectors. This gas sensing system was applied to analyse surrogate samples of natural fuel gas containing methane, ethane, propane and butane, quantified by using multivariate regression models based on partial least square (PLS) algorithms and Savitzky-Golay 1(st) derivative data preprocessing. The external validation of the obtained models reveals root mean square errors of prediction of 0.37, 0.36, 0.67 and 0.37% (v/v), for methane, ethane, propane and butane, respectively. The developed sensing system provides particularly rapid response times upon composition changes of the gaseous sample (approximately 2 s) due the minute volume of the iHWG-based measurement cell. The sensing system developed in this study is fully portable with a hand-held sized analyser footprint, and thus ideally suited for field analysis. Last but not least, the obtained results corroborate the potential of NIR-iHWG analysers for monitoring the quality of natural gas and petrochemical gaseous products. (AU) | |
| FAPESP's process: | 08/57808-1 - National Institute of Advanced Analytical Science and Technology |
| Grantee: | Celio Pasquini |
| Support Opportunities: | Research Projects - Thematic Grants |