Using the LIBS technique for the study of heavy metals in leachate liquid samples

• Grant number: 17/19248-3
• Support Opportunities: Regular Research Grants
• Duration: May 01, 2018 - December 31, 2020
• Field of knowledge: Physical Sciences and Mathematics - Physics
• Principal Investigator: Carlos Renato Menegatti
• Grantee: Carlos Renato Menegatti
• Host Institution: Embrapa Instrumentação Agropecuária. Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA). Ministério da Agricultura, Pecuária e Abastecimento (Brasil). São Carlos , SP, Brazil
• Associated researchers: Débora Marcondes Bastos Pereira ; Hélcio José Izário Filho ; Paulino Ribeiro Villas Boas

Abstract

In this project, we intend to use the single-pulse (SP) and the double-pulse (DP) LIBS (Laser-Induced Breakdown Spectroscopy) technique for detection of heavy metals in leachate liquid samples. Samples will be artificially contaminated with well-determined concentrations of the following metals: Pb, As, Cd, Mn. We intend to be able to solve the spectral lines of these elements and to correlate the peak intensities with reference concentration measurements made by the ICP-OES technique. With these spectra, we will construct calibration curves and determine the LIBS limits of detection for each species comparing the two techniques (SP x DP). The project also aims to create a faster, robust and economical for sample analysis compared to traditional techniques (ICP-OES and EDS) currently used. (AU)

Scientific publications

(6)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

MARANGONI, BRUNO S.; NICOLODELLI, GUSTAVO; SENESI, GIORGIO S.; FONSECA, NIELSEN; IZARIO FILHO, HELCIO J.; XAVIER, ALFREDO AUGUSTO; VILLAS-BOAS, PAULINO R.; MILORI, DEBORA M. B. P.; MENEGATTI, CARLOS R.. Multi-elemental analysis of landfill leachates by single and double pulse laser-induced breakdown spectroscopy. Microchemical Journal, v. 165, JUN 2021. (17/19248-3, 13/07276-1)

NICOLODELLI, GUSTAVO; VILLAS-BOAS, PAULINO R.; MENEGATTI, CARLOS R.; SENESI, GIORGIO S.; MAGALHAES, V, DANIEL; DE SOUZA, DANIELE; MILORI, DEBORA M. B. P.; MARANGONI, BRUNO S.. Determination of Pb in soils by double-pulse laser-induced breakdown spectroscopy assisted by continuum wave-diode laser-induced fluorescence. APPLIED OPTICS, v. 57, n. 28, p. 8366-8372, OCT 1 2018. (13/07276-1, 17/19248-3)

NICOLODELLI, GUSTAVO; CABRAL, JADER; MENEGATTI, CARLOS RENATO; MARANGONI, BRUNO; SENESI, GIORGIO S.. Recent advances and future trends in LIBS applications to agricultural materials and their food derivatives: An overview of developments in the last decade (2010-2019). Part I. Soils and fertilizers. TRAC-TRENDS IN ANALYTICAL CHEMISTRY, v. 115, p. 70-82, JUN 2019. (17/19248-3)

MENEGATTI, CARLOS R.; NICOLODELLI, GUSTAVO; SENESI, GIORGIO S.; DA SILVA, OTAVIO A.; FILHO, I, HELCIO J.; VILLAS-BOAS, PAULINO R.; MARANGONI, BRUNO S.; MILORI, DEBORA M. B. P.. Evaluation of LIBS under controlled atmosphere to quantify cadmium at low concentration in landfill leachates. APPLIED PHYSICS B-LASERS AND OPTICS, v. 125, n. 5, MAY 2019. (13/07276-1, 17/19248-3)

LEVA BORDUCHI, LUIS CARLOS; MENEGATTI, CARLOS RENATO; MILORI, DEBORA MARCONDES BASTOS PEREIRA; IZARIO FILHO, HELCIO JOSE; VILLAS-BOAS, PAULINO RIBEIRO. Application of one-point calibration LIBS for quantification of analytes in samples with distinct matrix characteristics: a case study with Hg. Journal of Analytical Atomic Spectrometry, v. 38, n. 5, p. 9-pg., 2023-03-17. (17/19248-3, 22/05451-0, 13/07276-1)

NICOLODELLI, GUSTAVO; HERCULANO, RONDINELLI D.; MARANGONI, BRUNO S.; RIBEIRO, MATHEUS C. S.; MILORI, DEBORA M. B. P.; MENEGATTI, CARLOS R.. Differentiation of latex biomembrane with collagen and non-collagen using laser induced breakdown spectroscopy. MATERIALS TODAY COMMUNICATIONS, v. 30, MAR 2022. (13/07276-1, 17/19603-8, 17/19248-3)