Multiferroic and ferroelectric materials for energy converters: synthesis, properties, phenomenology and applications

• Grant number: 17/13769-1
• Support Opportunities: Research Projects - Thematic Grants
• Start date: September 01, 2018
• End date: August 31, 2024
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: José Antonio Eiras
• Grantee: José Antonio Eiras
• Host Institution: Centro de Ciências Exatas e de Tecnologia (CCET). Universidade Federal de São Carlos (UFSCAR). São Carlos , SP, Brazil
• Pesquisadores principais: Eudes Borges de Araújo ; Ruth Herta Goldschmidt Aliaga Kiminami
• Associated researchers: Ana Maria do Espírito Santo ; Everaldo Nassar Moreira ; Fabio Luis Zabotto ; Filippo Ghiglieno ; Luiz Antonio Bássora ; Manuel Henrique Lente ; Mario Godinho Junior ; Rossano Lang Carvalho
• Associated research grant(s): 25/06589-3 - 21st International Conference on Diffusion in Solids and Liquids, AR.EXT; 24/08652-1 - 2024 IEEE Ultrasonics, Ferroelectrics, and Frequency Control Joint Symposium, AR.EXT; 22/06618-5 - Physical properties investigation of BiFeO3 multiferroic thin films and halide perovskites based on lead methylammonium iodide, AV.EXT; 19/14688-0 - Multiuser equipment (EMU), crystal growth furnace by Bridgman vertical static method, to be acquired through Thematic Project, FAPESP Proc. 2017/13769-1, AP.EMU
• Associated scholarship(s): 24/03661-2 - Growth and characterization of lead-free piezoelectric single crystals, BP.DD; 24/04150-1 - INFLUENCE OF DIFFERENT MAGNETIC PHASES ON MAGNETOELECTRIC COUPLING IN LEAD-FREE NANO HETEROSTRUCTURES, BP.DD; 24/06119-4 - Growth of multiferroic single crystals and characterization of their optical properties for piezophotonic applications, BP.DD; + associated scholarships 23/06088-9 - Structure and electrical properties of domains in ferroelectrics and multiferroic materials, BP.PD; 23/08484-9 - Determination of the effect of temperature and sintering time on the growth of lead-free piezoelectric single crystals produced by the seed-free solid state reaction route, BP.IC; 23/07654-8 - Effect of different magnetic phases on magnetoelectric coupling properties of nanostructures of (K0.5Na0.5)NbO3/(CoFe2O4, NiFe2O4 OR BaFe12O19) obtained by physical deposition, BP.DD; 23/05716-6 - Synthesis and Characterization of Ferroelectric and Multiferroic Materials for Applications in Energy Storage and Converters (Mechanical and Photovoltaic)", BP.TT; 22/05578-0 - Growth of multiferroic single crystals and characterization of optical properties for piezophotonic applications, BP.DD; 22/00821-3 - Structure and electrical properties of domains in multiferroic and ferroelectric materials, BP.PD; 22/04153-5 - Synthesis of (KxNa1-x)NbO3/CoFe2O4 nanostructures obtained by RF-sputtering, BP.IC; 22/00786-3 - Piezoelectric and electromechanical characterization of materials for mechanical to electric energy conversion, BP.IC; 22/00788-6 - Characterization of multiferroic nanostructured monoliths sintered via Spark Plasma Sintering - SPS, BP.DD; 21/01399-0 - Fabricação de nanoestruturas de (KxNa1-x)NbO3 /CoFe2O4 obtidas por rf-sputtering, BP.IC; 21/01406-7 - Development of spectroscopy techniques to investigate the effect of polarization on the propagation of light in ferroic materials, BP.PD; 20/06570-7 - Determination of the magnetoelectric coupling by analysis of the ferroelectric polarization curve in magnetoelectric and heterostructured systems, BP.IC; 20/05457-2 - Synthesis and dielectric and ferroelectric characterization of nanostructured PZT-based ferroelectric materials, BP.IC; 19/25921-8 - Microwave calcination of lead-free piezoelectric materials of the BCZT system, BP.IC; 19/26807-4 - Growth and characterization of lead free piezoelectric single crystals, BP.DD; 19/24458-2 - Investigation of the influence of La3 + concentration on the microstructural and structural properties of ferroelectric ceramics of (K0.48-x/2 Na0.52-x/2Lax)NbO3, BP.IC; 19/20487-8 - Manufacture of (KxNa1-x) NbO3 / CoFe2O4 nanostructures obtained by RF-sputtering, BP.IC; 19/16978-6 - Synthesis and characterization of physical properties of single-phase Pb(Fe,Nb)-Pb(Zr,Ti)O3 multiferroic ceramics, BP.IC; 19/12237-1 - Synthesis and characterization of nanoestrutured multiferroics bulk ceramics produced via Spark Plasma Sintering - SPS, BP.DD; 19/12278-0 - Synthesis by hydrothermal co-precipitation of Ta-doped KNLN and its microwave-assisted sintering, BP.IC; 19/03110-8 - Synthesis and photovoltaic characterization of thin films based on ferroelectric and multiferroic perovskite for solar cells application, BP.PD; 19/05844-9 - Synthesis and photovoltaic characterization of ferroic thin films, BP.IC; 19/05894-6 - Piezoelectric and electromechanical characterization of materials and mechanical into electric energy converters devices, BP.IC; 18/24133-3 - Processing and characterization of Pb(Fe,Nb)-PbTiO3 multiferroic ceramics, BP.IC - associated scholarships

Abstract

This multidisciplinary proposal aims to contribute to a significant qualitative and quantitative advance in the synthesis, characterization, modeling and applications of ferroic materials, monolithic and nanostructured, to enhance its properties for applications in renewable and magnetoelectric energy converters. The generation and use of energy from renewable sources is a strategic area for the country from a scientific, technological and economic point of view. Single-phase or composite ferroic materials will be developed for use in mechanical (electromechanical) or solar (photovoltaic) energy converters into electrical energy. Through an experimental approach (synthesis, processing and characterization) and theoretical (phenomenological modeling by Density Functional Theory) we intend to investigate multiferroic and ferroelectric materials, aiming at the maximization of some of its physical properties for the application in energy converting devices. Relevant contributions are expected in three fundamental pillars in the development of new materials and devices: methods of processing single crystals, bulk and two-dimensional materials, modeling of fundamental properties (structural / microstructure-property correlation) and prospective development of prototypes of new sensors, actuators and power converters. The results of this research, due to their comprehensive and innovative nature, will certainly contribute to the development of new class of materials.** This Project is part of the INCT "Materiais Ferroicos Nanoestruturados para Conversores de Energia", Chamada INCT - MCTI/CNPq/CAPES/FAPs nº 16/2014). (AU)

Scientific publications

(74)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

HOYOS, JOSE RODRIGO M.; BOTERO, ERITON R.; GARCIA, DUCINEI; KIMINAMI, RUTH H. G. A.. Simultaneous two-phase formation model in synthesized SBN/NFO using the in-situ modified Pechini method. CERAMICS INTERNATIONAL, v. 45, n. 7, A, p. 8593-8599, MAY 2019. (17/13769-1)

FERNANDEZ PERDOMO, CLAUDIA P.; ZABOTTO, FABIO L.; GARCIA, DUCINEI; KIMINAMI, RUTH H. G. A.. Effect of the CoFe2O4 initial particle size when sintered by microwave on the microstructural, dielectric, and magnetic properties. International Journal of Applied Ceramic Technology, v. 16, n. 5, SI, p. 2073-2084, SEP 2019. (17/13769-1)

DE ABREU, P. T. P.; DA COSTA VARGAS, N. F.; GENNARI, R. C.; LANG, R.; EIRAS, J. A.; LENTE, M. H.. Influence of the sintering temperature on the optical properties of Pb(Ti Ni)O3-delta and (K Ba)(Nb Ni)O3-delta ceramics. Ferroelectrics, v. 545, n. 1, SI, p. 97-108, JUN 11 2019. (17/13769-1)

REIS, S. P.; ARAUJO, E. B.. Dielectric relaxation and electrical conductivity of random oriented BiFeO3 thin films. Ferroelectrics, v. 545, n. 1, SI, p. 111-118, JUN 11 2019. (17/13769-1)

GUNNEWIEK, RODOLFO F. K.; PERDOMO, CLAUDIA P. F.; CANCELLIERI, IGOR C.; CARDOSO, ANDRE L. F.; KIMINAMI, RUTH H. G. A.. Microwave sintering of a nanostructured low-level additive ZnO-based varistor. CERAMICS INTERNATIONAL, v. 46, n. 10, A, p. 15044-15053, JUL 2020. (17/13769-1)

CORNELIUS, THOMAS W.; MOCUTA, CRISTIAN; ESCOUBAS, STEPHANIE; LIMA, LUIZ R. M.; ARAUJO, EUDES B.; KHOLKIN, ANDREI L.; THOMAS, OLIVIER. Piezoelectric Properties of Pb1-xLax(Zr0.52Ti0.48)(1-x/4)O(3)Thin Films Studied by In Situ X-ray Diffraction. MATERIALS, v. 13, n. 15, AUG 2020. (17/13769-1)

FREITAS, V. F.; ASTRATH, E. A. C.; DIAS, L. C.; MAZUR, M.; SOUZA, G. B.; BONADIO, T. G. M.; EIRAS, J. A.; SILVA, D. M.; ROHLING, J. H.; DIAS, G. S.; et al. On the Characteristics of Perovskite Structured BiFeO3-PbTiO3 Thin Films: Their Potential to Multifunctional Photovoltaic Applications. Brazilian Journal of Physics, v. 51, n. 4, p. 1215-1223, AUG 2021. (17/13769-1)

MINUSSI, F. B.; REIS, S. P.; ARAUJO, E. B.. DC bias electric field effects on ac electrical conductivity of MAPbI(3) suggesting intrinsic changes on structure and charge carrier dynamics. JOURNAL OF PHYSICS-CONDENSED MATTER, v. 33, n. 47, NOV 24 2021. (17/13769-1)

FREITAS, V. F.; EIRAS, J. A.; COTICA, L. F.; SANTOS, I. A.. Geometrical polarization approach: A semi-empirical tool to estimate the intrinsic polarization of polar dielectrics. CERAMICS INTERNATIONAL, v. 47, n. 1, p. 943-952, JAN 1 2021. (17/13769-1)

ALVES DA SILVA, GISLAYNE RAYANE; FERNANDEZ PERDOMO, CLAUDIA PATRICIA; KLEIN-GUNNEWIEK, RODOLFO FOSTER; GOLDSCHMIDT ALIAGA KIMINAMI, RUTH HERTA. Crystallization kinetic and structural characterization of lead-free piezoelectric 0.94(Na0.5Bi0.5)TiO3-0.06BaTiO(3) by polymeric precursor method. Materials Chemistry and Physics, v. 277, FEB 1 2022. (17/13769-1)

FERNANDEZ PERDOMO, CLAUDIA P.; KIMINAMI, RUTH H. G. A.; GARCIA, DUCINEI.. Microwave assisted sintering of nanocristalline PMN-PT/CoFe2O4 prepared by rapid one pot pechini synthesis: Dielectric and magnetoelectric characteristics. CERAMICS INTERNATIONAL, v. 45, n. 6, p. 7906-7915, APR 15 2019. (17/13769-1)

ALKATHY, MAHMOUD S.; LENTE, MANUEL H.; EIRAS, J. A.. Bandgap narrowing of Ba0.92Na0.04Bi0.04TiO3 ferroelectric ceramics by transition metals doping for photovoltaic applications. Materials Chemistry and Physics, v. 257, JAN 1 2021. (17/13769-1, 19/03110-8)

DE SOUZA, BRUNA G.; FIGUEIRA, GUSTAVO; CARVALHO, MARIA H.; ALCARAZ-GONZALEZ, VICTOR; SALDANA-FLORES, KARLA E.; GODINHO JR, MARIO; DE OLIVEIRA, ADILSON J. A.; KIMINAMI, RUTH H. G. A.; RUOTOLO, LUIS A. M.; URQUIETA-GONZALEZ, ERNESTO A.. A novel synthesis route to obtain magnetic nanocrystalline cobalt ferrite with photo-Fenton activity. Materials Chemistry and Physics, v. 257, JAN 1 2021. (13/07296-2, 17/13769-1, 17/24995-2, 09/54082-2)

GONZALEZ-ABREU, Y.; REIS, S. P.; FREITAS, F. E.; EIRAS, J. A.; ARAUJO, E. B.. Effects of crystallization kinetics on the dielectric and electrical properties of BiFeO3 films. JOURNAL OF ADVANCED DIELECTRICS, v. 11, n. 03, JUN 2021. (17/13769-1)

MINUSSI, F. B.; SILVA, L. A.; ARAUJO, E. B.. tructure, optoelectronic properties and thermal stability of the triple organic cation GA(x)FA(x)MA(1-2x)PbI(3) system prepared by mechanochemical synthesi. Physical Chemistry Chemical Physics, v. 24, n. 8, p. 4715-4728, FEB 23 2022. (17/13769-1)

ROESSLE, MATTHIAS; THOMAS, OLIVIER; MOCUTA, CRISTIAN; ROUSSET, RAPHAEL; TEXIER, MICHAEL; ESCOUBAS, STEPHANIE; DUBOURDIEU, CATHERINE; ARAUJO, EUDES B.; CORNELIUS, THOMAS W.. ime-resolved piezoelectric response in relaxor ferroelectric (Pb0.88La0.12)(Zr0.52Ti0.48)O-3 thin film. Journal of Applied Physics, v. 131, n. 6, FEB 14 2022. (17/13769-1)

D. M. S. CERON; C. P. F. PERDOMO; S. A. ELIZIARIO; M. J. KAUFMAN; R. H. G. A. KIMINAMI. Biphasic 0.8BaTiO3/0.2Ni(1-x)CoxFe2O4 nanopowders by in situ sol-gel synthesis. Cerâmica, v. 68, n. 385, p. 67-74, 2022-03-11. (17/13769-1)

ALIKIN, DENIS; FOMICHOV, YEVHEN; REIS, SAULO PORTES; ABRAMOV, ALEXANDER; CHEZGANOV, DMITRY; SHUR, VLADIMIR; ELISEEV, EUGENE; KALININ, SERGEI V.; MOROZOVSKA, ANNA; ARAUJO, EUDES B.; et al. Strain-polarization coupling mechanism of enhanced conductivity at the grain boundaries in BiFeO3 thin films. APPLIED MATERIALS TODAY, v. 20, SEP 2020. (17/13769-1)

TOGASHI, MARINA MAGRO; PERDOMO, CLAUDIA PATRICIA FERNANDEZ; KIMINAMI, RUTH H. G. A.. Effect of the Heating Rate and Processing Time on Grain Growth of Hematite Nanopowders in Conventional and Microwave-Assisted Sintering. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 26, p. 10-pg., 2023-01-01. (17/13769-1)

CARDOSO, ANDRE L. F.; PERDOMO, CLAUDIA P. F.; FOSCHIANI, BEATRIZ G.; BARBARA, IAGO C. S.; XARABA, JULIA A.; ZABOTTO, FABIO L.; GUNNEWIEK, RODOLFO F. K.. Microwave synthesis of nanostructured high entropy spinel. Materials Letters, v. 333, p. 4-pg., 2023-02-15. (17/13769-1)

ALKATHY, MAHMOUD. S.; RAHAMAN, ATTAUR; MASTELARO, VALMOR R.; ZABOTTO, FABIO. L.; MILTON, FLAVIO PAULO; EIRAS, J. A.. Achieving high energy storage density simultaneously with large efficiency and excellent thermal stability by defect dipole, and microstructural engineering in modified-BaTiO3 ceramics. Journal of Alloys and Compounds, v. 934, p. 13-pg., 2023-02-10. (19/03110-8, 22/00821-3, 17/13769-1)

PERDOMO, C. P. FERNANDEZ; MAZZETO, M.; KIMINAMI, R. H. G. A.. Novel rapid one-pot synthesis via complex polymerization of the biphasic lead-free system 0.5BaTi(0.92)Zr(0.08)O(3)/0.5Fe(2)CoO(4): Ba+2 and Co+2 precursor effect. Journal of Sol-Gel Science and Technology, v. 105, n. 1, p. 13-pg., 2022-11-17. (17/13769-1)

ALKATHY, MAHMOUD. S.; ALI, SYED MANSOOR; GOUD, J. PUNDAREEKAM; MASTELARO, VALMOR R.; ZABOTTO, FABIO. L.; MILTON, FLAVIO PAULO; STRABELLO, ALEXANDRE; RAJU, K. C. JAMES; EIRAS, J. A.. Achieving dense microstructure with desired physical properties rapidly and inexpensively in Bi-modified SrTiO₃ ceramics via microwave sintering technique. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 34, n. 22, p. 11-pg., 2023-08-01. (19/03110-8, 17/13769-1)

ALKATHY, MAHMOUD S.; PATTIPAKA, SRINIVAS; GATASHEH, MANSOUR K.; KASSIM, H. A.; SAAD DAOUD, MOHAMED; EIRAS, JOSE A.. Achieving high energy storage performance and efficiency in lead-free SrTiO₃ ceramics via neodymium and lithium co-doping technique. JOURNAL OF ASIAN CERAMIC SOCIETIES, v. N/A, p. 13-pg., 2023-09-18. (17/13769-1)

ALKATHY, MAHMOUD. S.; MILTON, FLAVIO PAULO; ZABOTTO, FABIO L.; GATASHEH, MANSOUR K.; KASSIM, H. A.; RAJU, K. C. JAMES; EIRAS, JOSE A.. Improve energy storage performance by tweaking grain size and widening the energy bandgap in modified BaTiO₃ ceramics. INDIAN JOURNAL OF PHYSICS, v. N/A, p. 14-pg., 2024-06-08. (23/05716-6, 17/13769-1)

MINUSSI, FERNANDO BRONDANI; SILVA JR, ROGERIO MARCOS; ARAUJO, EUDES BORGES. Composition-Property Relations for GA_xFA_yMA_1-x-yPbI₃ Perovskites. SMALL, v. 20, n. 7, p. 11-pg., 2023-10-06. (17/13769-1)

ALKATHY, MAHMOUD S.; PATTIPAKA, SRINIVAS; GATASHEH, MANSOUR K.; ZABOTTO, FABIO L.; EIRAS, JOSE A.. Manganese and Magnesium Co-doped Barium Titanate: A Route Towards Enhanced Energy Storage Performance via Defect Dipoles Engineering. Journal of Inorganic and Organometallic Polymers and Materials, v. 34, n. 3, p. 15-pg., 2023-10-12. (23/05716-6, 17/13769-1)

MINUSSI, F. B.; SILVA, R. M.; ARAUJO, E. B.. Interplay between cation composition and charge transport characteristics in GA_xFA_yMA_1-x-yPbI₃ halide perovskites. Applied Physics Letters, v. 124, n. 15, p. 6-pg., 2024-04-08. (17/13769-1)

ALKATHY, MAHMOUD S.; GATASHEH, MANSOUR K.; ZABOTTO, FABIO L.; KASSIM, H. A.; RAJU, K. C. JAMES; EIRAS, JOSE A.. Enhancing energy storage performance in BaTiO₃ ceramics via Mg and La co-doping strategy. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 35, n. 15, p. 11-pg., 2024-05-01. (23/05716-6, 17/13769-1)

HOYOS, JOSE RODRIGO M.; BOTERO, ERITON R.; GARCIA, DUCINEI; KIMINAMI, RUTH H. G. A.. Simultaneous two-phase formation model in synthesized SBN/NFO using the in-situ modified Pechini method. CERAMICS INTERNATIONAL, v. 45, n. 7, p. 7-pg., 2019-05-01. (17/13769-1)

FERNANDEZ PERDOMO, CLAUDIA P.; ZABOTTO, FABIO L.; GARCIA, DUCINEI; KIMINAMI, RUTH H. G. A.. Effect of the CoFe2O4 initial particle size when sintered by microwave on the microstructural, dielectric, and magnetic properties. International Journal of Applied Ceramic Technology, v. 16, n. 5, p. 12-pg., 2019-09-01. (17/13769-1)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; MILTON, FLAVIO PAULO; EIRAS, J. A.. Bandgap tuning in samarium-modified bismuth titanate by site engineering using iron and cobalt co-doping for photovoltaic application. Journal of Alloys and Compounds, v. 908, p. 10-pg., 2022-03-25. (19/03110-8, 17/13769-1)

MINUSSI, F. B.; BORGES, F. V. A.; ARAUJO, E. B.. Charge transport and dielectric characteristics of Sm (x) Bi1-x FeO3 thin films from the perspective of grain and grain boundary properties. JOURNAL OF PHYSICS D-APPLIED PHYSICS, v. 56, n. 35, p. 10-pg., 2023-08-31. (17/13769-1)

PERDOMO, C. P. F.; SUAREZ, A., V; GUNNEWIEK, R. F. K.; KIMINAMI, R. H. G. A.. Low temperature synthesis of high purity nanoscaled BiFeO3 by a fast polymer solution method and their ferromagnetic behavior. Journal of Alloys and Compounds, v. 849, p. 14-pg., 2020-12-30. (17/13769-1, 16/22350-1)

CAMINATA, LAIS P.; PERDOMO, CLAUDIA P. F.; KIMINAMI, RUTH H. G. A.. Effect of microwave heating during evaporation solvent and polymeric precursor formation in synthesis of BaZr0.08Ti0.92O3 nanopowders. Journal of Solid State Chemistry, v. 291, p. 12-pg., 2020-11-01. (17/13769-1)

ALKATHY, MAHMOUD S.; RAHAMAN, ATTAUR; MASTELARO, VALMOR R.; MILTON, FLAVIO PAULO; ZABOTTO, FABIO L.; LENTE, MANUEL H.; STRABELLO, ALEXANDRE; EIRAS, J. A.. Enhanced energy-storage density of BaTi0.95Zr0.05O3 via generation of defect dipoles upon lithium-doping. Materials Chemistry and Physics, v. 294, p. 12-pg., 2023-01-15. (19/03110-8, 22/00821-3, 17/13769-1)

FERNANDES, T. C.; GENNARI, R. C.; GELFUSO, M. V.; THOMAZINI, D.; AYALA, A. P.; EIRAS, J. A.; LENTE, M. H.. Growth and characterization of physical properties of photovoltaic (K,Ba)(Ni,Nb)O₃ single crystals. Ferroelectrics, v. 618, n. 5, p. 14-pg., 2024-04-03. (17/13769-1)

CAMINATA, LAIS P.; PERDOMO, CLAUDIA P. F.; ZABOTTO, FABIO L.; KIMINAMI, RUTH H. G. A.; EIRAS, JOSE A.. Multiferroic properties of lead-free magnetoelectric composites (1-X)BZT/(X)CFO synthesized by one-pot microwave-assisted Pechini method. CERAMICS INTERNATIONAL, v. 50, n. 24, p. 15-pg., 2024-12-03. (17/13769-1)

MINUSSI, F. B.; ARAUJO, E. B.. On the prospects of high-entropy organic A-site halide perovskites. Physical Chemistry Chemical Physics, v. 26, n. 41, p. 10-pg., 2024-10-03. (17/13769-1)

YAKUBU, SHEDRACH; MEIRELLES, MARIANA RODRIGUES; KOLAWOLE, FUNSHO OLAITAN; GONSALVES, MARAISA; EIRAS, J. A.; LENTE, M. H.. Synthesis of Er-Yb co-doped MgNb₂O6 ceramics and the exploration of their up-conversion photoluminescence and photocatalytic properties. Optical Materials, v. 163, p. 13-pg., 2025-06-01. (24/06119-4, 17/13769-1)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; MASTELARO, VALMOR R.; MILTON, FLAVIO PAULO; SILVA, DANIEL MATOS; SANTOS, IVAIR A.; EIRAS, J. A.. Band gap tuning in samarium-modified bismuth titanate ferroelectric via iron doping for photovoltaic applications. Ferroelectrics, v. 618, n. 4, p. 12-pg., 2024-03-11. (23/05716-6, 17/13769-1)

ALKATHY, MAHMOUD. S.; KASSIM, H. A.; GATASHEH, MANSOUR K.; GOUD, J. PUNDAREEKAM; EIRAS, JOSE A.. ACHIEVING SUPERIOR ENERGY STORAGE PERFORMANCE IN BARIUM TITANATE CERAMICS VIA A RARE EARTH CO-DOPING STRATEGY. CERAMICS-SILIKATY, v. 68, n. 4, p. 11-pg., 2024-01-01. (23/05716-6, 17/13769-1)

GUALDI, ALEXANDRE JOSE; BATACLINE, LEONARDO DOS SANTOS; SANTO, GUSTAVO CORREIA ESPIRITO; ALKATHY, MAHMOUD S.; ZABOTTO, FABIO LUIS. Synthesis and high-frequency magnetoelectric characterization of the 0-3 particulate lead-free multiferroic composite KNN/CFO. JOURNAL OF PHYSICS-CONDENSED MATTER, v. 36, n. 33, p. 7-pg., 2024-08-21. (19/24603-2, 23/05716-6, 17/13769-1)

BATISTA, G. C. DA S.; LENTE, M. H.. Sintering and characterization of dielectric and thermal mechanical properties of (Bi1/2Na1/2)TiO3-BaTiO3 ceramics. Ferroelectrics, v. 534, n. 1, SI, p. 29-41, OCT 3 2018. (17/13769-1)

GENNARI, RONALDO C.; LANG, ROSSANO; EIRAS, JOSE A.; LENTE, MANUEL H.. Effects of sintering process on the structural, dielectric, and optical absorption properties of KNbO3-based ceramics. Journal of the American Ceramic Society, v. 102, n. 7, p. 3923-3931, JUL 2019. (17/13769-1)

MINUSSI, F. B.; REIS, S. P.; ARAUJO, E. B.. An unusual frequency dispersion of the dielectric permittivity maxima at temperatures around the tetragonal-cubic phase transition of methylammonium lead iodide. Journal of Applied Physics, v. 127, n. 24, JUN 28 2020. (17/13769-1)

REIS, S. P.; FREITAS, F. E.; ARAUJO, E. B.. Processing of BiFeO3 thin films to control their dielectric response. Ferroelectrics, v. 560, n. 1, p. 61-69, MAY 18 2020. (17/13769-1)

GARCIA, LEONARDO ABREU; MORALES, SERGIO ANDRES VILLALBA; XAVIER, MICHELLE DA CUNHA ABREU; LOPES, MELINA SAVIOLI; SILVA, ELDA SABINO DA; MAIORANO, ALFREDO EDUARDO; GUNNEWIEK, RODOLFO FOSTER KLEIN; PERNA, RAFAEL FIRMANI. Synthesis and characterization of a novel silica-niobia support for the immobilization of microbial fructosyltransferase aiming at fructooligosaccharides production. MATERIALS TODAY COMMUNICATIONS, v. 31, p. 8-pg., 2022-06-01. (17/13769-1)

VARGAS, NATALIA F. C.; ALKATHY, MAHMOUD S.; EIRAS, JOSE A.; MASTELARO, VALMOR ROBERTO; LENTE, MANUEL H.. Sintering-driven effects on the band gap of (Pb,La)(Ti,Ni)O-3 photovoltaic ceramics. Journal of the American Ceramic Society, v. 104, n. 6, JAN 2021. (19/03110-8, 17/13769-1)

MINUSSI, FERNANDO B.; BERTOLETTI, EDUARDO M.; EIRAS, JOSE A.; ARAUJO, EUDES B.. Intrinsic aging in mixed-cation lead halide perovskites. SUSTAINABLE ENERGY & FUELS, v. 6, n. 21, p. 13-pg., 2022-09-19. (17/13769-1)

GUNNEWIEK, RODOLFO F. K.; PERDOMO, CLAUDIA P. F.; CANCELLIERI, IGOR C.; CARDOSO, ANDRE L. F.; KIMINAMI, RUTH H. G. A.. Microwave sintering of a nanostructured low-level additive ZnO-based varistor. CERAMICS INTERNATIONAL, v. 46, n. 10, p. 10-pg., 2020-07-01. (17/13769-1)

GATASHEH, MANSOUR K.; ALKATHY, MAHMOUD S.; KASSIM, HAMOUD ABDOH; GOUD, JAKKAPALLY PUNDAREEKAM; EIRAS, JOSE A.. Effect of gamma rays irradiation in the structure, optical, and electrical properties of samarium doped bismuth titanate ceramics. OPEN CHEMISTRY, v. 21, n. 1, p. 10-pg., 2023-09-29. (17/13769-1, 23/05716-6)

CANCELLIERI, IGOR C.; PERDOMO, CLAUDIA P. F.; MUCHE, DERECK N. F.; CORDEIRO, MARCO A. L.; GUNNEWIEK, RODOLFO F. K.. Synthesis of nanostructured sphere-like copper oxide by microwave spray pyrolysis. Materials Letters, v. 350, p. 5-pg., 2023-11-01. (17/13769-1)

GONCALVES, ANDRE MARINO; JIMENEZ, ROLANDO PLACERES; EIRAS, JOSE ANTONIO. Exploring the polarization reorientation in polycrystalline ferroelectric thin films from the macroscopic and nanoscopic perspectives. Journal of Alloys and Compounds, v. 880, NOV 5 2021. (17/13769-1, 13/03118-2)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; LENTE, MANUEL H.; EIRAS, J. A.. Octahedral distortion and oxygen vacancies induced band-gap narrowing and enhanced visible light absorption of Co/Fe co-doped Bi(3.25)Nd(0.75)Ti(3)O(12)ferroelectrics for photovoltaic applications. JOURNAL OF PHYSICS D-APPLIED PHYSICS, v. 53, n. 46, NOV 11 2020. (17/13769-1)

ALKATHY, MAHMOUD S.; ZABOTTO, FABIO L.; MILTON, FLAVIO PAULO; EIRAS, J. A.. Achieving high energy storage performance and breakdown strength in modified strontium titanate ceramics. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 33, n. 19, p. 12-pg., 2022-06-07. (19/03110-8, 17/13769-1)

MINUSSI, F. B.; DA SILVA, R. M.; ARAU, E. B.. Differing Effects of Mixed A-Site Composition on the Properties of Hybrid Lead Iodide Perovskites. Journal of Physical Chemistry C, v. 127, n. 18, p. 11-pg., 2023-04-28. (17/13769-1)

CARDOSO, ANDRE L. F.; PERDOMO, CLAUDIA P. F.; KIMINAMI, RUTH H. G. A.; GUNNEWIEK, RODOLFO F. K.. Enhancing the stabilization of nanostructured rocksalt-like high entropy oxide by Gd addition. Materials Letters, v. 285, FEB 15 2021. (17/13769-1)

BONINI, RICARDO PEREIRA; GUALDI, ALEXANDRA JOSE; EIRAS, JOSE ANTONIO; ZABOTTO, FABIO LUIS. Strain-induced modulation of magnetodielectric and magnetoelectric coupling in pzt/cfo thin films grown by rf-sputtering. Journal of Magnetism and Magnetic Materials, v. 552, p. 9-pg., 2022-02-25. (09/54082-2, 19/03110-8, 17/13769-1)

PERDOMO, CLAUDIA P. F.; ALMEIDA, DIOGENES F.; CANCELLIERI, IGOR C.; GARCIA, LEONARDO A.; CARDOSO, ANDRE L. F.; GUNNEWIEK, RODOLFO F. K.. Magnetic and electric behavior of spike- and petal-like nanoscaled Cu:ZnO superstructures diluted magnetic semiconductors. Materials Chemistry and Physics, v. 307, p. 11-pg., 2023-06-28. (17/13769-1)

ZABOTTO, FABIO L.; BARBOSA, VITOR F.; PEREIRA, CAROLYNE C. S.; ESTRADA, FLAVIA R.; LENTE, MANUEL H.; CHEN, XIANG MING; EIRAS, JOSE A.. Distinct magnetic contributions for magnetoelectric coupling at room temperature in perovskite PZT-PFN solid solutions. Journal of Alloys and Compounds, v. 929, p. 7-pg., 2022-12-25. (19/16978-6, 19/03110-8, 17/13769-1)

MINUSSI, F. B.; REIS, S. P.; ARAUJO, E. B.. Effects of frequency, temperature, and dc bias electric field on the dielectric properties of methylammonium lead iodide from the perspective of a relaxor-like ferroelectric. ACTA MATERIALIA, v. 219, OCT 15 2021. (17/13769-1)

LAVADO, C.; ALKATHY, MAHMOUD. S.; EIRAS, J. A.; STACHIOTTI, M. G.. Room-temperature multiferroic behavior in the three-layer Aurivillius compound Bi3.25La0.75Ti2Nb0.5(Fe1-x Co-x)(0.5)O-12. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, v. 129, n. 2, p. 10-pg., 2023-02-01. (19/03110-8, 17/13769-1)

ALKATHY, MAHMOUD S.; RAJESH, YALAMBAKU; KASSIM, H. A.; GATASHEH, MANSOUR K.; ZABOTTO, FABIO L.; RAJU, K. C. JAMES; EIRAS, JOSE A.. Enhancing energy storage performance in barium titanate ceramics through mg-doping via creation of defect dipoles engineering. JOURNAL OF THE AUSTRALIAN CERAMIC SOCIETY, v. N/A, p. 13-pg., 2024-09-04. (23/05716-6, 17/13769-1, 23/06088-9)

BATISTA, G. C. DA S.; LENTE, M. H.. Sintering and characterization of dielectric and thermal mechanical properties of (Bi1/2Na1/2)TiO3-BaTiO3 ceramics. Ferroelectrics, v. 534, n. 1, p. 13-pg., 2018-10-03. (17/13769-1)

MINUSSI, F. B.; SILVA JR, R. M.; CARVALHO, J. F.; ARAUJO, E. B.. Thermal degradation in methylammonium-formamidinium-guanidinium lead iodide perovskites. JOURNAL OF MATERIALS CHEMISTRY C, v. 12, n. 14, p. 12-pg., 2024-03-06. (17/13769-1)

FERNANDES, THISSIANA DA C.; EIRAS, JOSE A.; LENTE, MANUEL H.. Characterization of structural, chemical, and dielectric properties of (K, Na, Li)(Ta, Sb, Nb)O₃ single crystals grown by Bridgman-Stockbarger method. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 36, n. 10, p. 11-pg., 2025-04-01. (17/13769-1, 19/26807-4)

ALKATHY, MAHMOUD S.; RAJESH, YALAMBAKU; MILTON, FLAVIO PAULO; ZABOTTO, FABIO L.; MASTELARO, VALMOR R.; SILVA, DANIEL MATOS; SANTOS, IVAIR A.; EIRAS, J. A.. Achieving multiferroic properties in bismuth titanate ceramics via a tri-doping engineering mechanism with Co, Sm, and La at room temperature. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, v. 35, n. 23, p. 15-pg., 2024-08-01. (23/05716-6, 17/13769-1, 23/06088-9)

FERNANDES, THISSIANA DA CUNHA; THOMAZINI, DANIEL; GELFUSO, MARIA VIRGINIA; EIRAS, JOSE ANTONIO; AYALA, ALEJANDRO PEDRO; LENTE, MANUEL HENRIQUE. Correlation between thermal properties, growth parameters and low segregation coefficient in (K, Na)NbO3-based growth by Bridgman-Stockbarger route. MATERIALIA, v. 32, p. 8-pg., 2023-10-22. (17/13769-1, 19/26807-4)

REIS, S. P.; ARAUJO, E. B.. Dielectric relaxation and electrical conductivity of random oriented BiFeO3 thin films. Ferroelectrics, v. 545, n. 1, p. 8-pg., 2019-06-11. (17/13769-1)

DE ABREU, P. T. P.; DA COSTA VARGAS, N. F.; GENNARI, R. C.; LANG, R.; EIRAS, J. A.; LENTE, M. H.. Influence of the sintering temperature on the optical properties of Pb(Ti Ni)O3-delta and (K Ba)(Nb Ni)O3-delta ceramics. Ferroelectrics, v. 545, n. 1, p. 12-pg., 2019-06-11. (17/13769-1)

ALKATHY, MAHMOUD S.; MILTON, FLAVIO PAULO; GATASHEH, MANSOUR K.; ZABOTTO, FABIO LUIZ; KASSIM, H. A.; RAJU, K. C. JAMES; EIRAS, JOSE A.. Enhancing dielectric properties and thermal stability in microwave-synthesized Nd-modified barium titanate nanoceramics for possible MLCC applications. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, v. 130, n. 6, p. 13-pg., 2024-06-01. (23/05716-6, 17/13769-1)

MINUSSI, F. B.; SILVA JR, R. M.; MORAES, J. C. S.; ARAUJO, E. B.. Organic cations in halide perovskite solid solutions: exploring beyond size effects. Physical Chemistry Chemical Physics, v. 26, n. 31, p. 15-pg., 2024-07-24. (17/13769-1)

REIS, S. P.; ARAUJO, E. B.. Impact of defects on the electrical properties of BiFeO3 thin films. Ferroelectrics, v. 556, n. 1, SI, p. 70-78, FEB 17 2020. (17/13769-1)