Advanced spectroscopy of nanomaterials: from ensemble to single-particle

• Grant number: 18/15574-6
• Support Opportunities: Research Grants - Young Investigators Grants - Phase 2
• Start date: May 01, 2019
• End date: April 30, 2025
• Field of knowledge: Physical Sciences and Mathematics - Physics - Condensed Matter Physics
• Principal Investigator: Lázaro Aurélio Padilha Junior
• Grantee: Lázaro Aurélio Padilha Junior
• Host Institution: Instituto de Física Gleb Wataghin (IFGW). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated researchers: Diogo Burigo Almeida
• Associated research grant: 13/16911-2 - Advanced spectroscopy of novel nanomaterials, AP.JP
• Associated scholarship(s): 24/17527-6 - Fine-structure of NIR Nanoparticles, BP.PD; 23/09540-0 - Multi-Exciton and Multi-Photon Interactions in Perovskite Nanoplatelets, BP.MS; 23/02764-0 - Measuring ultrashort pulses using two-photon absorption, BP.IC; + associated scholarships 22/02736-3 - Single-particle spectroscopy of NIR nanoparticles, BP.PD; 21/13262-0 - Synthesis of Novel Perovskite Nanostructures, BP.PD; 20/14883-5 - Construction of an optical parametric amplifier, BP.IC; 20/14932-6 - Nonlinear optical properties of perovskite nanoparticles, BP.IC; 19/22576-8 - Accessing the excited state dynamics in nanostructures by multidimensional coherent spectroscopy, BP.PD; 19/22823-5 - Two-photon processes in quantum confined semiconductors, BP.MS - associated scholarships

Abstract

In the last two decades, colloidal semiconductor nanostructures are among the most investigated materials due to their unique set of properties, including the control of their optical and electronic properties by engineering their shape, size and composition, that turns them promising candidates for application in a vast range of areas, such as, energy harvesting, lighting, and Medicine. This project aims to contribute to the continuing development of semiconductor nanomaterials. By using advanced time-resolved spectroscopy methods, we will investigate multi-exciton interactions, carrier dynamics, nonlinear optical processes, and electron-phonon interactions in novel classes of visible and near infrared emitting nanomaterials. Moreover, by creating new synthetic routes we will grow perovskite nanomaterials with controlled size and shape. In particular, we propose to use a unique set of time-resolved spectroscopy techniques, including transient absorption, transient photoluminescence (also in single-particle regime), and two-dimensional transient four-wave-mixing to obtain deep understanding of the photo-physical processes in these nanomaterials, from the ensemble to the single-particle regime. This will shine light on several scientific questions that are still under debate in the literature, and will serve as guide to the wise development of nanomaterials tailored for specific applications. By the end of this project we expect to have answered relevant questions regarding the photo-physics is several nanomaterials systems including, but not restricted to, perovskite nanoparticles, InP-base core/shell, PbS/ZnS quantum dots, and CuInSxSe2-x nanostructures. (AU)

Scientific publications

(12)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

ALO, ARTHUR; BARROS, LEONARDO W. T.; NAGAMINE, GABRIEL; VIEIRA, LUCAS B.; CHANG, JUN HYUK; JEONG, BYEONG GUK; BAE, WAN KI; PADILHA, LAZARO A.. Simple Yet Effective Method to Determine Multiphoton Absorption Cross Section of Colloidal Semiconductor Nanocrystals. ACS PHOTONICS, v. 7, n. 7, p. 1806-1812, JUL 15 2020. (18/15574-6, 19/22823-5, 13/16911-2)

NAGAMINE, GABRIEL; FERREIRA, TOMAS A. C.; ALMEIDA, DIOGO B.; LEMUS, JONATHAN C.; CHANG, JUN HYUK; JEONG, BYEONG GUK; BAE, WAN KI; PADILHA, LAZARO A.. Sample Concentration Affects Optical Gain Results in Colloidal Nanomaterials: Circumventing the Distortions by Below Band Gap Excitation. ACS PHOTONICS, DEC 2021. (18/15574-6, 19/22565-6, 18/25339-4, 19/22576-8)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX(3)Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v. 59, n. 28, p. 11501-11509, JUL 6 2020. (14/50906-9, 18/15574-6, 17/11986-5, 13/16911-2)

CHANG, JUN HYUK; LEE, HAK JUNE; RHEE, SEUNGHYUN; HAHM, DONGHYO; JEONG, BYEONG GUK; NAGAMINE, GABRIEL; PADILHA, LAZARO A.; CHAR, KOOKHEON; HWANG, EUYHEON; BAE, WAN KI. Pushing the Band Gap Envelope of Quasi-Type II Heterostructured Nanocrystals to Blue: ZnSe/ZnSe1-XTeX/ZnSe Spherical Quantum Wells. ENERGY MATERIAL ADVANCES, v. 2021, p. 10-pg., 2021-01-01. (18/15574-6)

ALO, ARTHUR; BARROS, LEONARDO W. T.; NAGAMINE, GABRIEL; LEMUS, JONATHAN C.; PLANELLES, JOSEP; MOVILLA, JOSE L.; CLIMENTE, JUAN I.; LEE, HAK JUNE; BAE, WAN KI; PADILHA, LAZARO A.. Beyond Universal Volume Scaling: Tailoring Two-Photon Absorption in Nanomaterials by Heterostructure Design. Nano Letters, v. 23, n. 15, p. 8-pg., 2023-07-28. (18/15574-6, 18/25339-4, 19/22823-5)

BONATO, LUIZ GUSTAVO; DAL POGGETTO, GUILHERME; MORAL, RAPHAEL FERNANDO; DE CARVALHO VALE, BRENER RODRIGO; GERMINO, JOSE CARLOS; ALMEIDA, DIOGO BURIGO; SANTIAGO, PATRICIA; FERNANDEZ, PABLO SEBASTIAN; TORMENA, CLAUDIO FRANCISCO; PADILHA, LAZARO A.; et al. Photostability of amine-free CsPbBr3 perovskite nanocrystals under continuous UV illumination. JOURNAL OF MATERIALS CHEMISTRY C, v. 11, n. 24, p. 12-pg., 2023-03-06. (20/10246-0, 21/13262-0, 17/11986-5, 20/16077-6, 18/15574-6, 19/22576-8, 19/25765-6, 20/04431-0)

MORAL, RAPHAEL F.; MALFATTI-GASPERINI, ANTONIO A.; BONATO, LUIZ G.; VALE, BRENER R. C.; FONSECA, ANDRE F. V.; PADILHA, LAZARO A.; OLIVEIRA, CRISTIANO L. P.; NOGUEIRA, ANA F.. Self-assembly of perovskite nanoplates in colloidal suspensions. MATERIALS HORIZONS, v. N/A, p. 13-pg., 2023-10-05. (18/15574-6, 21/13262-0, 17/11986-5, 19/25765-6)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX3 Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, MAY 2020. (14/50906-9, 18/15574-6, 17/11986-5, 16/02268-9, 13/16911-2)

NAGAMINE, GABRIEL; JEONG, BYEONG GUK; FERREIRA, TOMAS A. C.; CHANG, JUN HYUK; PARK, KYOUNGWON; LEE, DOH C.; BAE, WAN KI; PADILHA, LAZARO A.. Efficient Optical Gain in Spherical Quantum Wells Enabled by Engineering Biexciton Interactions. ACS PHOTONICS, v. 7, n. 8, p. 2252-2264, AUG 19 2020. (18/15574-6, 18/25339-4, 19/22565-6, 13/16911-2)

LIU, ALBERT; NAGAMINE, GABRIEL; BONATO, LUIZ G.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; NOGUEIRA, ANA F.; PADILHA, LAZARO A.; CUNDIFF, STEVEN T.. Toward Engineering Intrinsic Line Widths and Line Broadening in Perovskite Nanoplatelets. ACS NANO, v. 15, n. 4, p. 8-pg., 2021-03-26. (18/15574-6, 19/22576-8)

SOUSA, CLAUDEVAN A.; BONATO, LUIZ G.; GONCALVES, EDUARDO S.; ALO, ARTHUR; VALE, BRENER R. C.; ALMEIDA, DIOGO B.; NOGUEIRA, ANA F.; ZAGONEL, LUIZ F.; PADILHA, LAZARO A.. Addressing the Magnitude of the Nonlinear Refraction Response in Perovskite Nanocrystals. ACS PHOTONICS, v. 10, n. 5, p. 7-pg., 2023-04-20. (17/11986-5, 20/06956-2, 22/06267-8, 18/15574-6, 21/13262-0, 18/08988-9, 20/16077-6, 19/22576-8, 21/06893-3, 18/25339-4)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX3 Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v. 59, n. 28, p. 9-pg., 2020-05-07. (17/11986-5, 14/50906-9, 13/16911-2, 18/15574-6, 16/02268-9)