Lignocellulosic biomass processing using ionic liquids for biorefinery application

• Grant number: 19/19976-4
• Support Opportunities: Scholarships in Brazil - Doctorate
• Start date: March 01, 2020
• End date: February 28, 2021
• Field of knowledge: Engineering - Chemical Engineering - Chemical Process Industries
• Principal Investigator: Marcus Bruno Soares Forte
• Grantee: Felipe Augusto Ferrari
• Host Institution: Faculdade de Engenharia de Alimentos (FEA). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Associated research grant: 15/50612-8 - An integrated approach to explore a novel paradigm for biofuel production from lignocellulosic feedstocks, AP.TEM

Abstract

Climate changes, due to the historical depletion of natural resources, have led us to rethink technology driving. The replacement of fossil fuels by renewable alternatives has been studied in order to mitigate the environmental impact of energy production. However, the use of lignocellulosic residues, such as Sugar Cane Straw (SW) for biofuels synthesis, demands pre-treatment, due to its complexity. The recent use of Ionic Liquids (IL) in this process emerges as a strategy to overcome the problems faced, such as high energy demand and inhibitory compounds production. In this context, this project proposes the use of protic, cheap and simple IL as pre-treatment strategy to valorize biomass in an economic and environmental sustainable way. In a pioneer study, the effect on pre-treatment of the major operational conditions reported in literature were assessed regarding residual solid chemical composition and enzymatic digestibility. IL purification and recycle strategy was proposed, which will be evaluated in the next block of experiments. Finally, process environmental and economic sustainability will be assessed, proposing a potential scope of products, adding value for the whole process. (AU)

Scientific publications

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

FERRARI, F. A.; NOGUEIRA, G. P.; FRANCO, T. T.; DIAS, M. O. S.; CAVALIERO, C. K. N.; WITKAMP, G. J.; VAN DER WIELEN, L. A. M.; FORTE, M. B. S.. The role of ionic liquid pretreatment and recycling design in the sustainability of a biorefinery: a sugarcane to ethanol example. GREEN CHEMISTRY, v. 23, n. 22, OCT 2021. (17/24520-4, 19/19976-4, 18/20173-0, 15/50612-8, 19/10439-6)

AUGUSTO, FERRARI FELIPE; FRANCISCO, MALARET; STEPHEN, EUSTACE; JASON, HALLETT; VAN DER WIELEN, LUUK; GEERT-JAN, WITKAMP; BRUNO, FORTE MARCUS. Physicochemical Characterization of Two Protic Hydroxyethylammonium Carboxylate Ionic Liquids in Water and Their Mixture. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 67, n. 6, p. 17-pg., 2022-06-09. (15/50612-8, 17/24520-4, 19/19976-4)

BARBOSA, FERNANDO CESAR; MARTINS, MANOELA; BRENELLI, LIVIA BEATRIZ; FERRARI, FELIPE AUGUSTO; SOARES FORTE, MARCUS BRUNO; RABELO, SARITA CANDIDA; FRANCO, TELMA TEIXEIRA; GOLDBECK, ROSANA. Screening of potential endoglucanases, hydrolysis conditions and different sugarcane straws pretreatments for cello-oligosaccharides production. Bioresource Technology, v. 316, p. 8-pg., 2020-11-01. (18/14223-5, 19/08542-3, 17/15477-8, 15/50612-8, 19/19976-4)

Academic Publications

(References retrieved automatically from State of São Paulo Research Institutions)

FERRARI, Felipe Augusto. Processamento de matéria-prima lignocelulósica utilizando líquidos iônicos para aplicação em biorrefinaria. 2021. Doctoral Thesis - Universidade Estadual de Campinas (UNICAMP). Faculdade de Engenharia de Alimentos Campinas, SP.