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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

A Novel Electrochemical Sensor Based on Printex L6 Carbon Black Carrying CuO/Cu2O Nanoparticles for Propylparaben Determination

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Author(s):
Goulart, Lorena A. [1] ; Guaraldo, Thais T. [1] ; Lanza, Marcos R. V. [1, 2]
Total Authors: 3
Affiliation:
[1] Univ Sao Paulo, Inst Quim Sao Carlos, POB 780, BR-13560970 Sao Paulo, SP - Brazil
[2] UNESP, Inst Nacl Tecnol Alternat Deteccao Avaliacao Toxi, Inst Quim, BR-14800900 Araraquara, SP - Brazil
Total Affiliations: 2
Document type: Journal article
Source: Electroanalysis; v. 30, n. 12, p. 2967-2976, DEC 2018.
Web of Science Citations: 3
Abstract

The paper reports the development of a new sensor based on Printex L6 (CPL6) carbon black modified with copper oxides (CuO/Cu2O) nanoparticles and its application towards the determination of Propylparaben (PP). In fact, it is the first report of its kind in the literature. The sensor was produced through the dispersion of CPL6 in dimethylformamide on glassy carbon electrode surface followed by CuO/Cu2O electrodeposition. The conditions of electrodeposition investigated included time and solution concentration of Cu (II). Morphological, structural and electrochemical characterizations of the sensor were performed. Under optimal conditions, wide linear range (1.0 to 35.0 mu mol L-1) was obtained in the detection of PP. The detection limit obtained was 0.46 mu mol L-1 (S/N=3). The CuO/Cu2O-CPL6/GCE sensor was found to be as sensitive as the high performance liquid chromatography in the determination of PP in both cosmetic and river water samples, in addition to being reproducible and stable. (AU)

FAPESP's process: 16/01937-4 - Synthesis of binary metal oxides (Nb, Zr, ta, Ru, mo and co) supported on amorphous carbon for the production of gas diffusion electrodes (GDE) for the electrosynthesis of H2O2 in situ in flow reactors
Grantee:Marcos Roberto de Vasconcelos Lanza
Support type: Regular Research Grants
FAPESP's process: 14/50945-4 - INCT 2014: National Institute for Alternative Technologies of Detection, Toxicological Evaluation and Removal of Micropollutants and Radioactivies
Grantee:Maria Valnice Boldrin
Support type: Research Projects - Thematic Grants
FAPESP's process: 16/08760-2 - Heterojunction of NiO/ZnO and CuO/ZnO applied at the PHOTOELETRODEGRADATION of trimethoprim and levofloxacin
Grantee:Lorena Athie Goulart
Support type: Scholarships in Brazil - Post-Doctorate
FAPESP's process: 14/11861-0 - Development of nanostructured electrochemical sensors for the determination of antibiotics in samples of environmental interest
Grantee:Thais Tasso Guaraldo
Support type: Scholarships in Brazil - Post-Doctorate
FAPESP's process: 17/10118-0 - Study and application of electrochemical technology for the analysis and degradation of endocrine interferents: materials, sensors, processes and scientific dissemination
Grantee:Marcos Roberto de Vasconcelos Lanza
Support type: Research Projects - Thematic Grants