Best practices for electrochemical characterization of supercapacitors

Author(s)

dos Santos, Joao Pedro Aguiar ; Rufino, Fernando Cesar ; Ota, Joao I. Yutaka ; Fernandes, Rodolfo C. ; Vicentini, Rafael ; Pagan, Cesar J. B. ; Da Silva, Leonardo Morais ; Zanin, Hudson

• Document type: Journal article
• Source: JOURNAL OF ENERGY CHEMISTRY; v. 80, p. 19-pg., 2023-02-21.

Abstract

We discuss here essential aspects of the experimental supercapacitors characterization by a series of well-known electrochemical methods. We are motivated by a considerable number of publications that misreport procedures and results. Authors often conceal or neglect essential information about the elec-trochemical analytical apparatus used and its configuration. The lack of such information may lead researchers, especially inexperienced ones, to misunderstand the procedures and results. Eventually, the misled electrochemical equipment configuration favors misinterpretation of data and low repro-ducibility rates. This paper aims to highlight these issues and clarify them. We explain fundamental con-cepts of some electrochemical analytical methods, such as cyclic voltammetry, galvanostatic charge- discharge, single potential step chronoamperometry, and electrochemical impedance spectroscopy, focusing on the supercapacitor field. Distinct configurations of electrical parameters are presented and discussed to highlight the effects of incorrect setup and uncover misleading results. We discuss how the electrochemical setup and data analyses matter in reliable data results for the supercapacitor.(c) 2022 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved. (AU)

• FAPESP's process: 17/11958-1 - CINE - Advanced Energy Storage Division
• Grantee: Rubens Maciel Filho
• Support Opportunities: Research Grants - Research Centers in Engineering Program
• FAPESP's process: 16/08645-9 - Interdisciplinary research activities in electric smart grids
• Grantee: João Bosco Ribeiro do Val
• Support Opportunities: Research Projects - Thematic Grants
• FAPESP's process: 14/02163-7 - Development of supercapacitors devices from graphene, carbon nanotubes and diamonds
• Grantee: Hudson Giovani Zanin
• Support Opportunities: Research Grants - Young Investigators Grants