Applications of NMR and infrared spectroscopies in the non-destructive analysis of products and agroindustrial processes

• Grant number: 21/12694-3
• Support Opportunities: Regular Research Grants
• Start date: May 01, 2022
• End date: July 31, 2024
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Luiz Alberto Colnago
• Grantee: Luiz Alberto Colnago
• Host Institution: Embrapa Instrumentação Agropecuária. Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA). Ministério da Agricultura, Pecuária e Abastecimento (Brasil). São Carlos , SP, Brazil

Abstract

Agriculture is one of the human activities that allowed the evolution of the human being as a society, as it is the main source of food, Feed, fiber and fuel (4F). Faced with the continuous increase in the human population, changes in climate patterns and rapidly dispersion of pests and diseases, agricultural research must not only increase productivity, but also generate higher quality products, with longer shelf life, and at the same time generate technologies so that production systems are increasingly less polluting. Thus, research in the agricultural area increasingly involves studies and knowledge of chemistry, physics and biology, not only as isolated disciplines, but also with all their complex interrelationships with traditional agricultural research such as agronomy, veterinary, among many others. Therefore, most of the current research in the agricultural area is multidisciplinary and multi-institutional, carried out in partnerships between researchers in the agricultural areas with researchers in the basic sciences and engineering. It is within this multidisciplinary scope and with multiple inter-institutional partnerships, with a focus on "green" technologies, that the objective of this research project is: Develop instrumentation and methods of low and high field nuclear magnetic resonance (NMR) and spectroscopy in the infrared, near and mid-infrared region, for non-destructive or non-invasive analysis, analyzes without or with minimal generation of toxic residues. These instruments and methods will be used to analyze both products originating in the field (4F) and products that are used in the field such as pesticides, fertilizers, etc. and in agro-industrial processes. In addition, this project also aims, when possible, to transform this knowledge into green technologies that can be used to benefit not only rural producers, agro-industries, but also the final consumer. (AU)

Scientific publications

(16)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

DA SILVA, POLLYANA FERREIRA; GOMES, BRUNA FERREIRA; SILVA LOBO, CARLOS MANUEL; CARMO, MARCELO; ROTH, CHRISTINA; COLNAGO, LUIZ ALBERTO. Composite Graphite-Epoxy Electrodes for In Situ Electrochemistry Coupling with High Resolution NMR. ACS OMEGA, v. 7, n. 6, p. 10-pg., 2022-01-31. (21/12694-3, 19/13656-8, 12/22281-9)

FLÁVIO V. C. KOCK; LUIZ A. COLNAGO. NMR Relaxometry Applied to Chemical Studies of Paramagnetic Metal Cation Complexes: Fundamentals and Applications. Journal of the Brazilian Chemical Society, v. 33, n. 6, p. 509-522, 2022-05-30. (12/23169-8, 19/13656-8, 18/16040-5, 21/12694-3, 15/16624-9)

CONSOLO, NARA R. B.; BARBOSA, LUIS C. G. S.; MORAES, TIAGO B.; BURAQUE, VICENTE M.; COLNAGO, LUIZ A.; QUEIROZ JUNIOR, LUIZ H. K.; OLIVEIRA, VITOR M.; HANNAFORD, RINA; ARAUJO, CRISTIANE S. S.; ROQUE, FABRICIA DE A.; et al. Using TD-NMR relaxometry to assess the effects of diet type and stocking rate on the incidence and degree of severity of myopathies in broilers. Microchemical Journal, v. 181, p. 9-pg., 2022-07-06. (20/08845-3, 21/12694-3)

SPRICIGO, POLIANA CRISTINA; ALMEIDA, LUISA SOUZA; RIBEIRO, GABRIEL HENRIQUE; CORREIA, BANNY SILVA BARBOSA; TAVER, ISABELA BARROSO; JACOMINO, ANGELO PEDRO; COLNAGO, LUIZ ALBERTO. Quality Attributes and Metabolic Profiles of Uvaia (Eugenia pyriformis), a Native Brazilian Atlantic Forest Fruit. FOODS, v. 12, n. 9, p. 17-pg., 2023-05-03. (14/12606-3, 22/08585-7, 18/00927-0, 21/12694-3)

YVES JOSÉ DE SOUZA SANTOS; NATALIA ALVES CAMPOS; GERSON BALBUENO BICCA; GISELE TEIXEIRA DE SOUZA SORA; LUIS FERNANDO POLESI; TANIA MARIA ALBERTE; POLIANA M. SANTOS; RODRIGO HENRIQUE DOS SANTOS GARCIA; LUIZ ALBERTO COLNAGO; GABRIELI OLIVEIRA-FOLADOR. Non-destructive determination of the oil content in peach palm (Bactris gasipaes) flour using NMR and NIR spectroscopies. FOOD SCIENCE AND TECHNOLOGY, v. 43, 2023-01-16. (19/13656-8, 21/12694-3)

GARCIA, RODRIGO HENRIQUE DOS SANTOS; FILGUEIRAS, JEFFERSON GONCALVES; COLNAGO, LUIZ ALBERTO; DE AZEVEDO, EDUARDO RIBEIRO. eal-Time Monitoring Polymerization Reactions Using Dipolar Echoes in H-1 Time Domain NMR at a Low Magnetic Fiel. Molecules, v. 27, n. 2, JAN 2022. (19/13656-8, 17/24465-3, 21/12694-3)

DE OLIVEIRA MACHADO, G.; TEIXEIRA, GUSTAVO GALASTRI; GARCIA, RODRIGO HENRIQUE DOS SANTOS; MORAES, TIAGO BUENO; BONA, EVANDRO; SANTOS, POLIANA M.; COLNAGO, LUIZ ALBERTO. Non-Invasive Method to Predict the Composition of Requeijao Cremoso Directly in Commercial Packages Using Time Domain NMR Relaxometry and Chemometrics. Molecules, v. 27, n. 14, p. 10-pg., 2022-07-01. (21/12694-3)

MORALES GOMEZ, JUAN FERNANDO; BRANDAO CONSOLO, NARA REGINA; ANTONELO, DANIEL SILVA; BELINE, MARIANE; GAGAOUA, MOHAMMED; HIGUERA-PADILLA, ANGEL; COLNAGO, LUIZ ALBERTO; GERRARD, DAVID EDWIN; SILVA, SAULO LUZ. Impact of Cattle Feeding Strategy on the Beef Metabolome. METABOLITES, v. 12, n. 7, p. 14-pg., 2022-07-01. (21/12694-3, 20/08845-3, 18/01434-8, 18/25320-1)

NASCIMENTO MITRE, CIRLEI IGREJA; GOMES, BRUNA FERREIRA; PARIS, ELAINE; SILVA LOBO, CARLOS MANUEL; ROTH, CHRISTINA; COLNAGO, LUIZ ALBERTO. Use of Time Domain Nuclear Magnetic Resonance Relaxometry to Monitor the Effect of Magnetic Field on the Copper Corrosion Rate in Real Time. MAGNETOCHEMISTRY, v. 8, n. 4, p. 10-pg., 2022-04-01. (21/12694-3, 19/13656-8, 12/22281-9)

SALVADOR, MARILIA VILELA; CRIZOSTOMO KOCK, FLAVIO VINICIUS; SANTOS, ISABELLA LAPORTE; CARVALHO PAULINO, JEAN FAUSTO; DE ALMEIDA, CALEO PANHOCA; DOS SANTOS GARCIA, RODRIGO HENRIQUE; BENCHIMOL-REIS, LUCIANA LASRY; COLNAGO, LUIZ ALBERTO; FERREIRA, ANTONIO GILBERTO. Monitoring Stimulated Darkening from UV-C Light on Different Bean Genotypes by NMR Spectroscopy. Molecules, v. 27, n. 7, p. 10-pg., 2022-04-01. (21/12694-3, 18/16040-5, 18/08582-2, 17/24711-4)

NASCIMENTO MITRE, CIRLEI IGREJA; TOSIN, GIANCARLO; COLNAGO, LUIZ ALBERTO. In-operando analysis of the corrosion patterns and rates under magnetic fields using metallic film. NPJ MATERIALS DEGRADATION, v. 6, n. 1, p. 7-pg., 2022-03-24. (21/12694-3, 19/13656-8)

FACCHINATTO, WILLIAM M.; ARAUJO, LEANDRO O.; MORAES, TIAGO B.; ABELHA, THAIS F.; LIMA, THALITA H. N.; DOS SANTOS, DANILO M.; CAMPANA-FILHO, SERGIO P.; COLNAGO, LUIZ A.; CAIRES, ANDERSON R. L.. Antimicrobial and Photoantimicrobial Activities of Chitosan/CNPPV Nanocomposites. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, v. 23, n. 20, p. 16-pg., 2022-10-01. (16/20970-2, 21/12694-3)

SANTOS, Y. J. S.; FACCHINATTO, W. M.; ROCHETTI, A. L.; CARVALHO, R. A.; LE FEUNTEUN, S.; FUKUMASU, H.; MORZEL, M.; COLNAGO, L. A.; VANIN, F. M.. Systemic characterization of pupunha (Bactris gasipaes) flour with views of polyphenol content on cytotoxicity and protein in vitro digestion. Food Chemistry, v. 405, p. 9-pg., 2023-03-30. (21/12694-3, 13/12693-0, 19/11479-1, 21/12270-9, 21/09897-0, 18/03324-5)

SANTOS, Y. J. S.; MALEGORI, C.; COLNAGO, L. A.; VANIN, F. M.. Application on infrared spectroscopy for the analysis of total phenolic compounds in fruits. CRITICAL REVIEWS IN FOOD SCIENCE AND NUTRITION, v. N/A, p. 11-pg., 2022-09-26. (21/12694-3, 19/11479-1, 21/12270-9, 18/03324-5, 13/12693-0)

DA SILVA, POLLYANA FERREIRA; RIBEIRO, TATIANA SANTANA; GOMES, BRUNA FERREIRA; DA SILVA, GELSON TIAGO DOS SANTOS TAVARES; LOBO, CARLOS MANUEL SILVA; CARMO, MARCELO; RIBEIRO, CAUE; FILHO, RUBENS BERNARDES; ROTH, CHRISTINA; COLNAGO, LUIZ ALBERTO. Miniaturized Carbon Fiber Paper Electrodes for In Situ High Resolution NMR Analyses. Analytical Chemistry, v. 94, n. 44, p. 8-pg., 2022-10-27. (21/12694-3)

DE SOUZA, ANA JULIA BORIM; OCAMPOS, FERNANDA MARIA MARINS; PULGROSSI, RAFAEL CATOIA; DOKKEDAL, ANNE LIGIA; COLNAGO, LUIZ ALBERTO; CECHIN, INES; SALDANHA, LUIZ LEONARDO. NMR-Based Metabolomics Reveals Effects of Water Stress in the Primary and Specialized Metabolisms of Bauhinia ungulata L. (Fabaceae). METABOLITES, v. 13, n. 3, p. 19-pg., 2023-03-01. (18/00504-2, 18/10734-5, 21/12694-3)