Advanced flow systems for technological, agronomical and environmental analysis

• Grant number: 11/23498-9
• Support Opportunities: Research Projects - Thematic Grants
• Start date: September 01, 2012
• End date: August 31, 2018
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Analytical Chemistry
• Principal Investigator: Elias Ayres Guidetti Zagatto
• Grantee: Elias Ayres Guidetti Zagatto
• Host Institution: Centro de Energia Nuclear na Agricultura (CENA). Universidade de São Paulo (USP). Piracicaba , SP, Brazil
• Pesquisadores principais: Boaventura Freire dos Reis ; Fábio Rodrigo Piovezani Rocha
• Associated researchers: Marcos Yassuo Kamogawa ; Wanessa Melchert Mattos
• Associated scholarship(s): 18/07687-5 - Exploitation of novel calibration strategies, digital images and flow analysis for biodiesel quality control, BP.DR; 17/08611-0 - Advances in sequential injection chromatography: two-dimensional chromatography and development of new stationary phases, BP.PD; 16/25333-0 - Development of flow systems for sample preparation applied to agronomic studies: determination of stress signaling species and nitrogen fractionation in leaf tissues, BP.PD; + associated scholarships 16/09899-4 - New strategies for gas-liquid separation in flow analysis, BP.PD; 16/00138-0 - Development of fast analytical procedures for biodiesel quality control, BP.MS; 13/26857-5 - Total concentrations and chemical speciation of As, Cr and Se using low pressure monolithic columns and inductively coupled plasma techniques, BP.PD; 13/22927-9 - Advanced oxidation processes in flow analysis., BP.PD; 13/00524-0 - Performance of extraction systems and flow analysis in exploring pulsed flow and fluidized bed, BP.DR; 10/00972-4 - Exploitation of pulsed flow and gas diffusion in a polyvalent analytical flow system: sulfide, sulfite and ethanol monitoring during alcoholic fermentation., BP.PD - associated scholarships

Abstract

The aim is to develop advanced flow systems for chemical analysis exploiting pulsed flows, novel strategies for micro-liquid-liquid extraction, solid-liquid and liquid-gas, micro-digestion, novel alternatives for the immobilization of reagents and solvents, more efficient exploitation of slow reactions and the construction of miniaturized instruments. The reduced consumption of reagents and the volume of waste generated will also be emphasized. Analytical procedures involve spectroanalytical detection techniques in flow injection, sequential injection, multi-pumping and/or multi-commuted flow systems. These systems will be applied to analysis of soils, natural waters, plants, foods, drugs, molasses, biodiesel, ethanol fuel and petroleum coke. The procedures should provide significant improvements in analytical performance, adding features to be more environmentally friendly, robust and portable (AU)

Scientific publications

(42)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SASAKI, MILTON K.; FERES, MARIO A.; ZAGATTO, ELIAS A. G.. Flow Systems with MnO2-coated Open Tubular Reactors for Spectrophotometric Determination of Ascorbic Acid in Pharmaceutical Products. Analytical Letters, v. 49, n. 5, SI, p. 627-638, MAR 23 2016. (11/14413-0, 11/23498-9)

PEREIRA, ANDREIA C.; ROCHA, FABIO R. P.. Liquid-liquid microextraction in a multicommuted flow system for direct spectrophotometric determination of iodine value in biodiesel. Analytica Chimica Acta, v. 829, p. 28-32, JUN 4 2014. (11/23498-9)

SILVA, AMANDA R. M.; KAMOGAWA, MARCOS Y.; MELCHERT, WANESSA R.. A versatile and greener multicommuted flow-based system for exploiting relatively slow chemical reactions. Microchemical Journal, v. 133, p. 121-125, JUL 2017. (11/23498-9)

DIAS, TUANNE R.; SASAKI, MILTON K.; ZAGATTO, ELIAS A. G.. Dual thermostating in flow analysis. Talanta, v. 168, p. 303-306, JUN 1 2017. (11/23498-9, 14/25198-0)

ROCHA, DIOGO L.; KAMOGAWA, MARCOS Y.; ROCHA, FABIO R. P.. A critical review on photochemical conversions in flow analysis. Analytica Chimica Acta, v. 896, p. 11-33, OCT 8 2015. (11/23498-9)

MELCHERT, WANESSA R.; ROCHA, FABIO R. P.. Cloud point extraction in flow-based systems. REVIEWS IN ANALYTICAL CHEMISTRY, v. 35, n. 2, p. 41-52, JUL 2016. (11/23498-9)

VIDA, ANA C. F.; COCOVI-SOLBERG, DAVID J.; ZAGATTO, ELIAS A. G.; MIRO, MANUEL. Rapid estimation of readily leachable triazine residues in soils using automatic kinetic bioaccessibility assays followed by on-line sorptive clean-up as a front-end to liquid chromatography. Talanta, v. 156, p. 71-78, AUG 15 2016. (14/09842-7, 11/23498-9)

SILVA, CLAUDINEIA R.; GOMES, TACIANA F.; BARROS, VALDEMIR A. F.; ZAGATTO, ELIAS A. G.. A multi-purpose flow manifold for the spectrophotometric determination of sulphide, sulphite and ethanol involving gas diffusion: Application to wine and molasses analysis. Talanta, v. 113, p. 118-122, SEP 15 2013. (10/00972-4, 11/23498-9)

DIAS, TUANNE R.; MELCHERT, WANESSA R.; KAMOGAWA, MARCOS Y.; ROCHA, FABIO R. P.; ZAGATTO, ELIAS A. G.. Fluidized particles in flow analysis: potentialities, limitations and applications. Talanta, v. 184, p. 325-331, JUL 1 2018. (14/25198-0, 11/23498-9)

SOARES, SAMARA; MELCHERT, WANESSA R.; ROCHA, FABIO R. P.. A flow-based procedure exploiting the lab-in-syringe approach for the determination of ester content in biodiesel and diesel/biodiesel blends. Talanta, v. 174, p. 556-561, NOV 1 2017. (16/00138-0, 11/23498-9)

LIMA, MANOEL J. A.; REIS, BOAVENTURA F.. Fully automated photometric titration procedure employing a multicommuted flow analysis setup for acidity determination in fruit juice, vinegar, and wine. Microchemical Journal, v. 135, p. 207-212, NOV 2017. (11/23498-9)

BATISTA, ALEX D.; ROCHA, FABIO R. P.. On-column preconcentration in sequential injection chromatography: application to determination of parabens. ANALYTICAL METHODS, v. 7, n. 10, p. 4371-4375, 2015. (11/06437-6, 11/23498-9)

SANTOS, FELISBERTO G.; PEREIRA, ANDREIA C.; CRUZ, SANDRA M.; BIZZI, CEZAR A.; FLORES, ERICO M. M.; REIS, BOAVENTURA F.. Development of a multicommuted flow analysis procedure for simultaneous determination of sulfate and chloride in petroleum coke employing a homemade syringe pump and a LED-based photometer. ANALYTICAL METHODS, v. 7, n. 11, p. 4769-4779, 2015. (13/05728-2, 11/23498-9)

SASAKI, MILTON K.; ROCHA, DIOGO L.; ROCHA, FABIO R. P.; ZAGATTO, ELIAS A. G.. Tracer-monitored flow titrations. Analytica Chimica Acta, v. 902, p. 123-128, JAN 1 2016. (11/14413-0, 11/23498-9)

SANTOS, JORGE LUIS O.; LEITE, OLDAIR D.; VIEIRA, ANETE D. M.; JESUS, DJANE S.; KAMOGAWA, MARCOS Y.. Use of a Digital Image in Flow Analysis: Determination of Nitrite and Nitrate in Natural Waters. Journal of the Brazilian Chemical Society, v. 27, n. 1, p. 70-76, JAN 2016. (11/23498-9, 05/00878-0)

COLZATO, MARINA; KAMOGAWA, MARCOS Y.; CARVALHO, HUDSON W. P.; ALLEONI, LUIS R. F.; HESTERBERG, DEAN. Temporal Changes in Cadmium Speciation in Brazilian Soils Evaluated Using Cd L-III-Edge XANES and Chemical Fractionation. JOURNAL OF ENVIRONMENTAL QUALITY, v. 46, n. 6, p. 1206-1214, NOV-DEC 2017. (11/23498-9)

LIMA, MANOEL J. A.; KAMOGAWA, MARCOS Y.; REIS, BOAVENTURA F.. A new sensitive photometric procedure for the determination of sulfate in fuel ethanol without sample preparation exploiting a flow-batch strategy. Microchemical Journal, v. 145, p. 921-926, MAR 2019. (11/23498-9)

NASCIMENTO, CARINA F.; ROCHA, FABIO R. P.. Spectrofluorimetric determination of bisphenol A in tap waters by exploiting liquid-liquid microextraction in a sequential injection system. Microchemical Journal, v. 137, p. 429-434, MAR 2018. (11/23498-9)

MARCOS Y. KAMOGAWA; JEOVÁ CORREIA MIRANDA. Uso de hardware de código fonte aberto "Arduino" para acionamento de dispositivo solenoide em sistemas de análises em fluxo. Química Nova, v. 36, n. 8, p. 1232-1235, 2013-00-00. (12/08205-8, 11/23498-9)

LIMA, MANOEL J. A.; REIS, BOAVENTURA F.. Automatic Procedure to Determine Acidity in Fuel Ethanol by Photometric Titration Using Binary Search and Multicommuted Flow Analysis. Journal of the Brazilian Chemical Society, v. 29, n. 11, p. 2326-2333, NOV 2018. (11/23498-9)

OLIVEIRA, ELIEZER; HENRIQUEZ, CAMELIA; NUNES, LIDIANE C.; ZAGATTO, ELIAS A. G.. Exploiting multivariate calibration for compensation of iron interference in the spectrophotometric flow-based catalytic determination of molybdenum. Talanta, v. 179, p. 15-21, MAR 1 2018. (11/23498-9)

LIMA, MANOEL J. A.; REIS, BOAVENTURA F.; ZAGATTO, ELIAS A. G.; KAMOGAWA, MARCOS Y.. An automatic titration setup for the chemiluminometric determination of the copper complexation capacity in opaque solutions. Talanta, v. 209, MAR 1 2020. (11/23498-9)

LIMA, MANOEL J. A.; REIS, BOAVENTURA F.. Photogeneration of silver nanoparticles induced by UV radiation and their use as a sensor for the determination of chloride in fuel ethanol using a flow-batch system. Talanta, v. 201, p. 373-378, AUG 15 2019. (11/23498-9)

COLZATO, MARINA; FERRACCIU ALLEONI, LUIS REYNALDO; KAMOGAWA, MARCOS YASSUO. Cadmium sorption and extractability in tropical soils with variable charge. ENVIRONMENTAL MONITORING AND ASSESSMENT, v. 190, n. 6, JUN 2018. (11/19944-3, 12/08205-8, 11/23498-9)

SASAKI, MILTON K.; SOUZA, PEDRO A. F.; KAMOGAWA, MARCOS Y.; REIS, BOAVENTURA F.; ROCHA, FABIO R. P.. A new strategy for membraneless gas-liquid separation in flow analysis: Determination of dissolved inorganic carbon in natural waters. Microchemical Journal, v. 145, p. 1218-1223, MAR 2019. (16/09899-4, 11/23498-9)

DAMINATO, BIANCA; KAMOGAWA, MARCOS Y.; MELCHERT, WANESSA R.. An Environmental Friendly Flow-Injection Procedure for On Line Extraction and Spectrophotometric Determination of Gossypol in Cottonseed Meal. Journal of the Brazilian Chemical Society, v. 28, n. 11, p. 2094-2099, NOV 2017. (11/14071-1, 11/23498-9)

SILVA, CLAUDINEIA RODRIGUES; HENRIQUEZ, CAMELIA; FRIZZARIN, REJANE MARA; GUIDETTI ZAGATTO, ELIAS AYRES; CERDA, VICTOR. A critical comparison of constant and pulsed flow systems exploiting gas diffusion. Talanta, v. 148, p. 596-601, FEB 1 2016. (11/23498-9)

FRIZZARIN, REJANE M.; PORTUGAL, LINDOMAR A.; ESTELA, JOSE M.; ROCHA, FABIO R. P.; CERDA, VICTOR. On-line lab-in-syringe cloud point extraction for the spectrophotometric determination of antimony. Talanta, v. 148, p. 694-699, FEB 1 2016. (11/23498-9)

RENATA S. AMAIS; FÁBIO R. P. ROCHA; JOAQUIM A. NÓBREGA. Sinais de fundo em análise instrumental: uma discussão essencial em cursos de graduação. Química Nova, v. 40, n. 2, p. 228-237, 2017-02-00. (13/26857-5, 11/23498-9)

ROCHA, FABIO R. P.; BATISTA, ALEX D.; MELCHERT, WANESSA R.; ZAGATTO, ELIAS A. G.. Solid-phase extractions in flow analysis. Anais da Academia Brasileira de Ciências, v. 90, n. 1, 1, p. 803-824, 2018. (11/23498-9)

CRISPINO, CARLA C.; KAMOGAWA, MARCOS Y.; FERREIRA, JOSE R.; ZAGATTO, ELIAS A. G.. Sulphate radical generation through interaction of peroxymonosulphate with Co(II) for in-line sample preparation aiming at spectrophotometric flow-based determination of phosphate and phosphite in fertilizers. Talanta, v. 158, p. 270-275, SEP 1 2016. (13/22927-9, 11/23498-9)

ROCHA, DIOGO L.; MACHADO, MARCOS C.; MELCHERT, WANESSA R.. A sensitive flow-based procedure for spectrophotometric speciation analysis of inorganic bromine in waters. Talanta, v. 129, p. 93-99, NOV 1 2014. (11/14071-1, 11/23498-9)

PEREIRA, ANDREIA C.; REIS, BOAVENTURA F.; ROCHA, FABIO R. P.. An air carrier flow system for the spectrophotometric determination of water in biodiesel exploiting bleaching of the cobalt chloride complex. Talanta, v. 131, p. 21-25, JAN 2015. (11/23498-9)

GONZALEZ, PABLO; KNOCHEN, MOISES; SASAKI, MILTON K.; ZAGATTO, ELIAS A. G.. Pulsed flows in flow analysis: Potentialities, limitations and applications. Talanta, v. 143, p. 419-430, OCT 1 2015. (11/14413-0, 11/23498-9)

BATISTA, ALEX D.; ROCHA, FABIO R. P.. A flow injection low-pressure chromatographic system exploiting fused-core columns. ANALYTICAL METHODS, v. 6, n. 23, p. 9299-9304, 2014. (11/06437-6, 11/23498-9)

BATISTA, ALEX D.; SASAKI, MILTON K.; ROCHA, FABIO R. P.; ZAGATTO, ELIAS A. G.. Flow analysis in Brazil: contributions over the last four decades. ANALYST, v. 139, n. 15, p. 3666-3682, 2014. (11/06437-6, 11/14413-0, 11/23498-9)

VIDA, ANA C. E.; ZAGATTO, ELIAS A. G.. Exploiting Zone Trapping to Avoid Liberation of Air Bubbles in Flow-based Analytical Procedures Requiring Heating. Analytical Sciences, v. 30, n. 8, p. 833-838, AUG 2014. (11/08011-6, 11/23498-9)

ADAME, ANDRESSA; ROCHA, FABIO R. P.. A multi-pumping flow system for acute toxicity bioassay using the Vibrio fischeri bacteria. ANALYTICAL METHODS, v. 6, n. 18, p. 7367-7373, 2014. (11/23498-9)

AMARAL, CLARICE D. B.; AMAIS, RENATA S.; FIALHO, LUCIMAR L.; SCHIAVO, DANIELA; AMORIM, TATIANE; NOGUEIRA, ANA RITA A.; ROCHA, FABIO R. P.; NOBREGA, JOAQUIM A.. A novel strategy to determine As, Cr, Hg and V in drinking water by ICP-MS/MS. ANALYTICAL METHODS, v. 7, n. 3, p. 1215-1220, 2015. (13/26857-5, 11/23498-9)

AMAIS, RENATA S.; TEIXEIRA, LEONARDO S. G.; ROCHA, FABIO R. P.. Greener procedures for biodiesel quality control. ANALYTICAL METHODS, v. 7, n. 11, p. 4396-4418, 2015. (13/26857-5, 11/23498-9)

MACHADO, JEANE M. C.; MELCHERT, WANESSA R.; ZAGATTO, ELIAS A. G.; KAMOGAWA, MARCOS Y.. A Multi-Pumping Flow System with Pulsed Fluidization to Evaluate Soil Capacity for Phosphate Adsorption. Journal of the Brazilian Chemical Society, v. 28, n. 7, p. 1149-1157, JUL 2017. (13/00524-0, 11/19944-3, 12/08205-8, 11/23498-9)

SASAKI, MILTON K.; FERES, MARIO A.; ZAGATTO, ELIAS A. G.. Flow Systems with MnO2-coated Open Tubular Reactors for Spectrophotometric Determination of Ascorbic Acid in Pharmaceutical Products. Analytical Letters, v. 49, n. 5, p. 12-pg., 2016-03-23. (11/23498-9, 11/14413-0)