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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Liquid-liquid equilibrium data for the system limonene plus carvone plus ethanol + water at 298.2 K

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Author(s):
Oliveira, Cassia M. [1] ; Koshima, Cristina C. [1] ; Capellini, Maria C. [1] ; Carvalho, Fernanda H. [1] ; Aracava, Keila K. [1] ; Goncalves, Cintia B. [1] ; Rodrigues, Christianne E. C. [1]
Total Authors: 7
Affiliation:
[1] Univ Sao Paulo, Dept Food Engn ZEA FZEA, Separat Engn Lab LES, BR-13635900 Pirassununga, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: Fluid Phase Equilibria; v. 360, p. 233-238, DEC 25 2013.
Web of Science Citations: 16
Abstract

This paper presents experimental liquid-liquid equilibrium data at 298.2 K for systems composed of limonene, carvone and hydrous ethanol with five different levels of water in the solvent. The experimental data were correlated using the NRTL and UNIQUAC models, and both thermodynamic equations provided good descriptive quality. In the parameter correlation procedure, mean deviations between the calculated and experimental data of less than 0.0037 were obtained for systems with major contents of water in the solvent. With respect to systems that contained lower concentrations of water in the solvent, we predicted the phase compositions by considering the previously obtained set of parameters. The experimental results showed that as the water content in the solvent phase was increased, the values of the limonene and carvone distribution coefficients decreased. However, the oxygenated compound always exhibited a greater distribution coefficient value. The addition of water to the system also influenced the phase splitting region, and the increased water content in the solvent is responsible for making deterpenation of the essential oil using ethanol a feasible process. (C) 2013 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 10/03235-0 - Liquid-liquid equilibria thermodynamic modeling of systems composed by limonene, carvone, ethanol and water
Grantee:Cássia Maria de Oliveira
Support type: Scholarships in Brazil - Scientific Initiation
FAPESP's process: 09/17271-1 - Liquid-liquid equilibria study for systems composed by components of origanum essential oil and alcoholic solvent
Grantee:Maria Carolina Capellini
Support type: Scholarships in Brazil - Scientific Initiation
FAPESP's process: 11/02476-7 - Essential oils deterpenation by solvent extraction: experimental study and process simulation
Grantee:Christianne Elisabete da Costa Rodrigues
Support type: Regular Research Grants
FAPESP's process: 10/20789-0 - Deterpenation of essential oils by liquid-liquid extraction using a perforated rotating disc column: experimental study and process simulation
Grantee:Cristina Chiyoda Koshima
Support type: Scholarships in Brazil - Doctorate