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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Excess enthalpies for pseudobinary mixtures containing vegetable oils at the temperatures 298.15 K, 353.15 K and 383.15 K

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Author(s):
Belting, Patricia C. [1, 2] ; Gmehling, Jurgen [2] ; Bolts, Rainer [2] ; Rarey, Jurgen [2] ; Ceriani, Roberta [3] ; Chiavone-Filho, Osvaldo [4] ; Meirelles, Antonio J. A. [1]
Total Authors: 7
Affiliation:
[1] Univ Estadual Campinas, Fac Food Engn, Dept Food Engn, BR-13083862 Campinas, SP - Brazil
[2] Carl von Ossietzky Univ Oldenburg, Tech Chem, D-26111 Oldenburg - Germany
[3] Univ Estadual Campinas, Fac Chem Engn, BR-13083852 Campinas, SP - Brazil
[4] Univ Fed Rio Grande do Norte, Dept Chem Engn, BR-59066800 Natal, RN - Brazil
Total Affiliations: 4
Document type: Journal article
Source: Fluid Phase Equilibria; v. 375, p. 124-133, AUG 15 2014.
Web of Science Citations: 1
Abstract

This paper presents excess enthalpies for the following systems containing refined vegetable oils: soybean oil + methanol (at 353.15 K/722 kPa), soybean oil + ethanol (at 353.15 K/687 kPa and 383.15 K/653 kPa), soybean oil + n-hexane (at 353.15 K/722 kPa and 383.15 K/756 kPa), soybean oil + propan-2-ol (at 298.15 K/998 kPa), sunflower oil + methanol (at 353.15 K/791 kPa), sunflower oil + ethanol (at 353.15 K/894 kPa and 383.15 K/860 kPa), sunflower oil + n-hexane (at 353.15 K/756 kPa and 383.15 K/894 kPa), sunflower oil + propan-2-ol (at 298.15 K/929 kPa), rapeseed oil + methanol (at 353.15 K/963 kPa), rapeseed oil + ethanol (at 353.15 K/998 kPa and 383.15 K/1136 kPa), and rapeseed oil + n-hexane (at 353.15 K/894 kPa and 383.15 K/1136 kPa). The measurements were carried out with a commercially available isothermal flow calorimeter. The experimental H-E values have been correlated using the Redlich-Kister polynomial equation. The results for systems with propan-2-ol and some values of partial molar excess enthalpies at infinite dilution, H-i(E,infinity), obtained in this study have been compared to those available in the literature. The results were also discussed in terms of molecular interactions. (C) 2014 Elsevier B.V. All rights reserved. (AU)

FAPESP's process: 09/54137-1 - Acquisition of a particle size/distribution analyzer, a zeta potential measurement system, a spray dryer, and an ultra-high-pressure liquid chromatograph/mass spectrometer
Grantee:Miriam Dupas Hubinger
Support type: Multi-user Equipment Program
FAPESP's process: 10/16634-0 - Separation processes by stripping in the fat and oil industry
Grantee:Roberta Ceriani
Support type: Regular Research Grants
FAPESP's process: 08/56258-8 - Phase equilibrium and purification processes in the production of biofuels and biocompounds
Grantee:Antonio José de Almeida Meirelles
Support type: Program for Research on Bioenergy (BIOEN) - Thematic Grants