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(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Fractionation of lemon essential oil by solvent extraction: Phase equilibrium for model systems at T=298.2 K

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Author(s):
Koshima, Cristina C. [1] ; Capellini, Maria C. [1] ; Geremias, Ivana M. [1] ; Aracava, Keila K. [1] ; Goncalves, Cintia B. [1] ; Rodrigues, Christianne E. C. [1]
Total Authors: 6
Affiliation:
[1] Univ Sao Paulo, Dept Food Engn ZEA FZEA, LES, BR-13635900 Pirassununga, SP - Brazil
Total Affiliations: 1
Document type: Journal article
Source: JOURNAL OF CHEMICAL THERMODYNAMICS; v. 54, p. 316-321, NOV 2012.
Web of Science Citations: 20
Abstract

The fractioning of lemon essential oil can be performed by liquid-liquid extraction using hydrous ethanol as a solvent. A quaternary mixture composed of limonene, gamma-terpinene, beta-pinene, and citral was used to simulate lemon essential oil. In this paper, we present (liquid + liquid) equilibrium data that were experimentally determined for systems containing essential oil compounds, ethanol, and water at T = 298.2 K. The experimental data were correlated using the NRTL and UNIQUAC models, and the mean deviations between calculated and experimental data were less than 0.0053 in all systems, indicating the accuracy of these molecular models in describing our systems. The results show that as the water content in the solvent phase increased, the values of the distribution coefficients decreased, regardless of the type of compound studied. However, the oxygenated compound always showed the highest distribution coefficient among the components of the essential oil, thus making deterpenation of the lemon essential oil a feasible process. (C) 2012 Elsevier Ltd. All rights reserved. (AU)

FAPESP's process: 11/02476-7 - Essential oils deterpenation by solvent extraction: experimental study and process simulation
Grantee:Christianne Elisabete da Costa Rodrigues
Support type: Regular Research Grants
FAPESP's process: 09/07910-7 - Physical properties of systems composed by essential oils and alcoholic solvents: experimental data, modelling and prediction
Grantee:Ivana Morais Geremias de Andrade
Support type: Scholarships in Brazil - Scientific Initiation
FAPESP's process: 08/07326-0 - Deterpenation of lemon and bergamot peel oils: experimental data and modeling of liquid-liquid equilibria
Grantee:Cristina Chiyoda Koshima
Support type: Scholarships in Brazil - Master
FAPESP's process: 09/17271-1 - Liquid-liquid equilibria study for systems composed by components of origanum essential oil and alcoholic solvent
Grantee:Maria Carolina Capellini
Support type: Scholarships in Brazil - Scientific Initiation
FAPESP's process: 10/20789-0 - Deterpenation of essential oils by liquid-liquid extraction using a perforated rotating disc column: experimental study and process simulation
Grantee:Cristina Chiyoda Koshima
Support type: Scholarships in Brazil - Doctorate