Scientific studies and innovation application on CVD diamond, DLC and carbon nanostructures obtained by chemical vapor deposition technique

• Grant number: 12/15857-1
• Support Opportunities: Research Projects - Thematic Grants
• Duration: October 01, 2013 - September 30, 2019
• Field of knowledge: Engineering - Materials and Metallurgical Engineering - Nonmetallic Materials
• Principal Investigator: Vladimir Jesus Trava-Airoldi
• Grantee: Vladimir Jesus Trava-Airoldi
• Host Institution: Instituto Nacional de Pesquisas Espaciais (INPE). Ministério da Ciência, Tecnologia e Inovações (Brasil). São José dos Campos , SP, Brazil
• Pesquisadores principais: Evaldo Jose Corat
• Associated researchers: Anderson de Oliveira Lobo ; Edson Del Bosco ; Elidiane Cipriano Rangel da Cruz ; Enzo Granato ; Erica Freire Antunes ; Fernanda Roberta Marciano ; Getúlio de Vasconcelos ; João Roberto Moro ; Leonidas Lopes de Melo ; Manfredo Harri Tabacniks ; Milton Sergio Fernandes de Lima ; Nelia Ferreira Leite ; Nilson Cristino da Cruz ; Rudimar Riva
• Associated grant(s): 14/12508-1 - Scientific studies and innovative applications on CVD-diamond, diamond-like carbon (DLC) and nano structured carbon, obtained by chemical vapor deposition, AP.EMU; 14/01708-0 - Nanosmat USA, AR.EXT
• Associated scholarship(s): 19/08473-1 - Development of carbon nanotubes supercapacitors for applications in lead-acid battery, BP.DD; 18/06819-5 - Nanostructured composite boron-doped diamond/carbon nanotubes applied as electrode for degradation of textile dye via electrochemical advanced oxidation process, BP.DR; 17/08899-3 - DLC films in multilayer with electric conductive nanoparticles for spatial and industrial applications, BP.DD; + associated scholarships 17/04598-9 - Application of intermediate or bonding coatings in machining inserts, by laser methods, for anchoring CVD diamond film, BP.PD; 17/04706-6 - Polymeric nanocomposites from polycaprolactone and carbon nanotubes: electrospinning parameters optimization, BP.IC; 15/26651-3 - Development of immunosensors for Alzheimer's biomarkers electrochemical detection, BP.PD; 16/07288-8 - Improvement studies of a pulsed DC PECVD system with additional cathode for DLC films deposit high adherence and enhanced properties on metal substrates, BP.PD; 16/07912-3 - Development of a microfluidic System of nanocomposite diamond/carbon nanotubes for atmosphere water harvesting., BP.DR; 15/24923-6 - Durability evaluation of diamond coating on inserts with complex geometries, BP.IC; 15/25149-2 - Study of vanadium carbide interface developed by thermodiffusion and laser cladding for HFCVD diamond deposition., BP.DR; 15/09781-0 - Study of DLC film growth inside of long tubes by pulsed-DC PECVD method, BP.PD; 15/02960-7 - Optimization study of large electrochemical active area of nanocomposites VACNT-GO and its application in capacitive deionization, BP.DD; 14/18139-8 - Growth and doping studies of mono-crystalline CVD-diamond, dye-colored via discharge of high-power mW 2.45 GHz, BP.PD; 13/25539-0 - Adherence optimization of DLC films grown on industrial application steels, BP.DR; 13/25939-8 - Study of interfaces by laser cladding for CVD diamond deposition, BP.DR; 13/22458-9 - Deposition of DLC (Diamond Like Carbon) films on tool steel AISI D2 and AISI H13, for general industrial applications, BP.DR - associated scholarships

Abstract

The main subject of this project is in carbon films as CVD diamond, DLC, and carbon nanostructures. For this project we considered the good results of two other priori thematic projects within this same area. In this way, our focus will be on continuing and improving the projects now in progress at the National Institute for Space Research - INPE and in other institutions. This project will address the issues in question within a context of research focused on fundamentals and their applications and, also, including product developments that lead to innovation. The main emphasizes will be on: developing methods for CVD diamond deposition in polycrystalline form with micro and nano structure and single crystal growth; studying new methods to obtain interfaces for CVD-Diamond and Diamond-like Carbon (DLC), with improved properties on metal surfaces and; studying carbon nanotube (CNT), graphene oxide (GO), reduced graphene oxide (RGO) growth and their interactions in composite structures and as biological material. Further emphasis will be on the fundamental tribology studies as a characterization technique for industrial and space applications, on the electrochemical study with boron, nitrogen and sulfur doped CVD diamond, DLC, NTC, GO and RGO electrodes for energy storage applications, treatment of effluents and finally for electrical power thermionic conversion. Many previous results of our project group have opened new ways, which ensures continuity of fundamental research with clear opportunities for technology transfer to the productive sector with high potential for innovation, as has happened previously. The financial support needed is for acquisition of some new equipments, updates, materials and services for characterizations and for improving new reactors in studies with scientific and technological innovation. It is also to help on students' formation, and, also, aiming expansion of national and international cooperation. (AU)

Scientific publications

(25)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

SILVA, AMANDA ARAUJO; PINHEIRO, ROMARIO ARAUJO; RAZZINO, CLAUDIA DO AMARAL; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Thin-film nanocomposites of BDD/CNT deposited on carbon fiber. DIAMOND AND RELATED MATERIALS, v. 75, n. SI, p. 116-122, MAY 2017. (15/02960-7, 12/15857-1)

SILVA, AMANDA ARAUJO; PINHEIRO, ROMARIO ARAUJO; RAZZINO, CLAUDIA DO AMARAL; CONTIN, ANDRE; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Synthesis and Characterization of Carbon Fiber Based Porous CNTs-RGO/BDD for Application as Microelectrodes. MRS ADVANCES, v. 2, n. 41, p. 2247-2252, 2017. (15/02960-7, 12/15857-1)

FRAGA, M. A.; CONTIN, A.; RODRIGUEZ, L. A. A.; VIEIRA, J.; CAMPOS, R. A.; CORAT, E. J.; TRAVA AIROLDI, V. J.. Nano- and microcrystalline diamond deposition on pretreated WC-Co substrates: structural properties and adhesion. MATERIALS RESEARCH EXPRESS, v. 3, n. 2, FEB 2016. (13/25939-8, 14/18139-8, 12/15857-1)

DIAS, VANESSA; MACIEL, HOMERO; FRAGA, MARIANA; LOBO, ANDERSON O.; PESSOA, RODRIGO; MARCIANO, FERNANDA R.. Atomic Layer Deposited TiO2 and Al2O3 Thin Films as Coatings for Aluminum Food Packaging Application. MATERIALS, v. 12, n. 4, FEB 2 2019. (14/18139-8, 11/50773-0, 11/17877-7, 12/15857-1, 11/20345-7, 16/00575-1, 15/05956-0, 15/09697-0, 18/01265-1, 15/10876-6)

SILVA, AMANDA ARAUJO; PINHEIRO, ROMARIO ARAUJO; RODRIGUES, ALINE CASTILHO; BALDAN, MAURICIO RIBEIRO; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Graphene sheets produced by carbon nanotubes unzipping and their performance as supercapacitor. Applied Surface Science, v. 446, n. SI, p. 201-208, JUL 15 2018. (15/02960-7, 12/15857-1)

PILLACA, E. J. D. M.; RAMIREZ, M. A.; GUTIERREZ BERNAL, J. M.; LUGO, D. C.; TRAVA-AIROLDI, V. J.. DLC deposition inside of a long tube by using the pulsed-DC PECVD process. SURFACE & COATINGS TECHNOLOGY, v. 359, p. 55-61, FEB 15 2019. (15/09781-0, 12/15857-1)

PINHEIRO, ROMARIO ARAUJO; ROSA, FILIPE MENEZES; VOLU, RENE MARTINS; DE VASCONCELOS, GETULIO; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Vertically aligned carbon nanotubes (VACNT) surfaces coated with polyethylene for enhanced dew harvesting. DIAMOND AND RELATED MATERIALS, v. 107, AUG 2020. (12/15857-1, 16/07912-3)

PINHEIRO, ROMARIO ARAUJO; SILVA, AMANDA ARAUJO; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Water vapor condensation and collection by super-hydrophilic and super-hydrophobic VACNTs. DIAMOND AND RELATED MATERIALS, v. 87, p. 43-49, AUG 2018. (16/07912-3, 12/15857-1)

WACHESK, C. C.; SEABRA, S. H.; DOS SANTOS, T. A. T.; TRAVA-AIROLDI, V. J.; LOBO, A. O.; MARCIANO, F. R.. In vivo biocompatibility of diamond-like carbon films containing TiO2 nanoparticles for biomedical applications. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, v. 32, n. 9, SEP 2021. (11/20345-7, 12/15857-1)

HURTADO, CAROLINA RAMOS; WACHESK, CRISTIANE DA COSTA; QUEIROZ, RAFAELA CAMPOS; DE MACEDO, ERENILDA FERREIRA; BORJA DE OLIVEIRA CORREIA, REBECA FALCAO; TAIARIOL, THALITA SANI; DINIZ, MILTON FARIA; ISAIAS DOS SANTOS, ALEXANDRE MARTINS; DO AMARAL MONTANHEIRO, THAIS LARISSA; HURTADO, GABRIELA RAMOS; et al. A simple procedure to obtain nanodiamonds from leftover of HFCVD system for biological application. SN APPLIED SCIENCES, v. 2, n. 3, MAR 2020. (12/15857-1, 17/01697-6)

LOPES, F. S.; OLIVEIRA, J. R.; MILANI, J.; OLIVEIRA, L. D.; MACHADO, J. P. B.; TRAVA-AIROLDI, V. J.; LOBO, A. O.; MARCIANO, F. R.. Biomineralized diamond-like carbon films with incorporated titanium dioxide nanoparticles improved bioactivity properties and reduced biofilm formation. Materials Science & Engineering C-Materials for Biological Applications, v. 81, p. 373-379, DEC 1 2017. (12/15857-1, 11/17877-7, 11/20345-7, 14/11491-8, 15/09697-0, 16/00575-1)

PINHEIRO, R. A.; DAMM, D. D.; SILVA, A. A.; VOLU, R. M.; ALMEIDA, K. F.; ROSA, F. M.; TRAVA-AIROLDI, V. J.; CORAT, E. J.. Water Vapor Condensation from Atmospheric Air by Super-Hydrophobic VACNTs Growth on Stainless Steel Pipes. MRS ADVANCES, v. 4, n. 35, SI, p. 1929-1936, 2019. (12/15857-1, 16/07912-3)

WACHESK, C. C.; TRAVA-AIROLDI, V. J.; DA-SILVA, N. S.; LOBO, A. O.; MARCIANO, F. R.. The Influence of Titanium Dioxide on Diamond-Like Carbon Biocompatibility for Dental Applications. Journal of Nanomaterials, 2016. (11/20345-7, 13/20054-8, 12/15857-1, 11/17877-7)

VIEIRA, JOSE; CONTIN, ANDRE; FRAGA, MARIANA AMORIM; CORAT, EVALDO JOSE; AIROLDI, VLADIMIR TRAVA. Growth and characterization of multilayer hot-filament chemical vapor deposition diamond coatings on WC-Co substrates. SURFACE INNOVATIONS, v. 7, n. 1, p. 4-11, MAR 2019. (14/18139-8, 13/25939-8, 12/15857-1)

DAMM, DJOILLE DENNER; CONTIN, ANDRE; BARBIERI, FERNANDO CRUZ; TRAVA-AIROLDI, VLADIMIR JESUS; BARQUETE, DANILO MACIEL; CORAT, EVALDO JOSE. Interlayers Applied to CVD Diamond Deposition on Steel Substrate: A Review. COATINGS, v. 7, n. 9, SEP 2017. (15/25149-2, 13/25939-8, 12/15857-1)

LUGO, D. C.; SILVA, P. C.; RAMIREZ, M. A.; PILLACA, E. J. D. M.; RODRIGUES, C. L.; FUKUMASU, N. K.; CORAT, E. J.; TABACNIKS, M. H.; TRAVA-AIROLDI, V. J.. Characterization and tribologic study in high vacuum of hydrogenated DLC films deposited using pulsed DC PECVD system for space applications. SURFACE & COATINGS TECHNOLOGY, v. 332, p. 135-141, DEC 15 2017. (12/15857-1)

DAMM, D. D.; CONTIN, A.; CARDOSO, L. D. R.; TRAVA-AIROLDI, V. J.; BARQUETE, D. M.; CORAT, E. J.. A novel method to mitigate residual stress in CVD diamond film on steel substrates with a single intermediate layer. SURFACE & COATINGS TECHNOLOGY, v. 357, p. 93-102, JAN 15 2019. (15/25149-2, 12/15857-1)

PESSOA, R. S.; DOS SANTOS, V. P.; CARDOSO, S. B.; DORIA, A. C. O. C.; FIGUEIRA, F. R.; RODRIGUES, B. V. M.; TESTONI, G. E.; FRAGA, M. A.; MARCIANO, F. R.; LOBO, A. O.; et al. TiO2 coatings via atomic layer deposition on polyurethane and polydimethylsiloxane substrates: Properties and effects on C. albicans growth and inactivation process. Applied Surface Science, v. 422, p. 73-84, NOV 15 2017. (11/50773-0, 12/15857-1, 11/17877-7, 11/20345-7, 15/10876-6, 15/09697-0, 15/08523-8, 16/00575-1, 15/05956-0)

CONTIN, ANDRE; DE VASCONCELOS, GETULIO; DAMM, DJOILLE D.; TRAVA-AIROLDI, VLADIMIR J.; CAMPOS, RAONEI A.; CORAT, EVALDO J.. Composite intermediate layer for CVD diamond film on steel substrate. MRS ADVANCES, v. 2, n. 41, p. 2211-2216, 2017. (13/25939-8, 12/15857-1)

SILVA, AMANDA ARAUJO; PINHEIRO, ROMARIO ARAUJO; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Influence of catalyst particles on multi-walled carbon nanotubes morphology and structure. FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, v. 26, n. 5, p. 315-323, 2018. (15/02960-7, 12/15857-1)

DAMM, D. D.; CONTIN, A.; GOMES, M. C. C. B.; TRAVA-AIROLDI, V. J.; BARQUETE, D. M.; CORAT, E. J.. Adherent HFCVD diamond on steels substrates using vanadium carbide intermediate layer. DIAMOND AND RELATED MATERIALS, v. 89, p. 218-226, OCT 2018. (15/25149-2, 12/15857-1)

PILLACA, E. J. D. M.; TRAVA-AIROLDI, V. J.; RAMIREZ, M. A.. Axial distribution improvements of DLC film on the inner surface of a long stainless steel tube. SURFACE & COATINGS TECHNOLOGY, v. 412, APR 25 2021. (12/15857-1, 15/09781-0)

BRAGA, THYAGO SANTOS; VIEIRA, NIRTON C. S.; ANTONELLI, EDUARDO; ROSA, FILIPE MENEZES; DONADON, MAURICIO VICENTE; CORAT, EVALDO JOSE. Development and study of low-cost VACNT/PDMS stretchable and resistive strain sensor. SENSORS AND ACTUATORS A-PHYSICAL, v. 315, NOV 1 2020. (12/15857-1, 18/07508-3)

RIBEIRO CARDOSO, LAYS DIAS; CARVAJAL BRAVO GOMES, MARINES CHIQUINQUIRA; ANTUNES, ERICA FREIRE; SILVA, FABIO SANTOS; TRAVA-AIROLDI, VLADIMIR JESUS; CORAT, EVALDO JOSE. Fast carbon nanotube growth on carbon fiber keeping tensile strength. COMPOSITE INTERFACES, v. 28, n. 9, p. 859-878, SEP 2 2021. (12/15857-1)

J. V. SILVA NETO; J. S. GÓMEZ; E. J. CORAT; V. J. TRAVA-AIROLDI. Growth and Characterization of Polycrystalline CVD Diamond Films Obtained by MWPACVD at High Power 2,45GHz Microwave Discharge. MATERIALS RESEARCH-IBERO-AMERICAN JOURNAL OF MATERIALS, v. 25, 2022-09-05. (19/18572-7, 12/15857-1)