Advanced search
Start date
Betweenand
(Reference retrieved automatically from Web of Science through information on FAPESP grant and its corresponding number as mentioned in the publication by the authors.)

Effect of Multi-Walled Carbon Nanotubes Incorporation on the Structure, Optical and Electrochemical Properties of Diamond-Like Carbon Thin Films

Full text
Author(s):
Zanin, H. [1, 2] ; May, P. W. [1] ; Lobo, A. O. [3] ; Saito, E. [2] ; Machado, J. P. B. [2] ; Martins, G. [2] ; Trava-Airoldi, V. J. [2] ; Corat, E. J. [2]
Total Authors: 8
Affiliation:
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon - England
[2] Natl Inst Space Res, BR-12227010 Sao Paulo - Brazil
[3] UNIVAP, Inst Res & Dev, Lab Biomed Nanotechnol, BR-12244000 Sao Paulo - Brazil
Total Affiliations: 3
Document type: Journal article
Source: Journal of the Electrochemical Society; v. 161, n. 5, p. H290-H295, 2014.
Web of Science Citations: 20
Abstract

We report the effect of incorporation of multi-walled carbon nanotubes (MWCNT) on the mechanical, structural, optical and electrochemical properties of diamond-like carbon (DLC) thin films The DLC/MWCNT hybrid composite was deposited onto stainless steel and quartz substrates by plasma enhanced chemical vapor deposition at low temperature (similar to 100 degrees C). Raman spectra of DLC/MWCNT film have characteristics from both DLC and MWCNT. The optical bandgap energy decreases with the incorporation of nanotubes. Scanning electron microscopy images confirm the presence of the M1WCNT within the DLC film, forming a large interconnected conducting mesh. Tribological tests confirm there was slight adherence loss with incorporating MWCNT into the DLC films, while improving their electrical conductivity. Electrochemical assays show the incorporation of MWCNT converts DLC from an insulating material into a reversible electrode with fast charge transfer. This novel hybrid composite is shown to be mechanically robust, chemically inert and exhibits fast charge-transfer kinetics, which is very promising for several new applications. (C) 2014 The Electrochemical Society. All rights reserved. (AU)

FAPESP's process: 11/17877-7 - Development of new polymeric scaffolds by electrospinning technique with incorporation of vertically aligned carbon nanotubes and nanohidroxyapatite for bone tissue regeneration
Grantee:Anderson de Oliveira Lobo
Support Opportunities: Research Grants - Young Investigators Grants