Development of a process of vegetable oil extraction using alcoholic solvents: evaluation of oil composition and changes in the protein fraction

• Grant number: 14/09446-4
• Support Opportunities: Regular Research Grants
• Start date: February 01, 2015
• End date: January 31, 2017
• Field of knowledge: Agronomical Sciences - Food Science and Technology - Food Engineering
• Principal Investigator: Christianne Elisabete da Costa Rodrigues
• Grantee: Christianne Elisabete da Costa Rodrigues
• Host Institution: Faculdade de Zootecnia e Engenharia de Alimentos (FZEA). Universidade de São Paulo (USP). Pirassununga , SP, Brazil
• Associated researchers: Carmen Sílvia Fávaro Trindade ; Cintia Bernardo Gonçalves ; Paulo José do Amaral Sobral

Abstract

The present research project has the aim of analyzing the technical viability of replacing hexane, a commonly used solvent in vegetable oil extraction, by short chain alcohols. The solvents proposed in this study, ethanol and isopropanol, are generally regarded as safe (GRAS), and this characteristic is a marked advantage in relation to the high toxicity and inflammability of hexane. Besides, these solvents are replacements that may be more easily recovered after the extraction process, as they are partially miscible in oil at room temperature. Although some advantages of replacing hexane by alcoholic solvents are evident, there are gaps to be filled by the systematic study of the process. In other research projects supported by FAPESP (06/00565-4, 09/17855-3, 10/03058-1, 10/13285-5), the adequate conditions to make the use of alcoholic solvents viable in the extraction of soybean and rice bran oil, and the influence of the process variables were evaluated in the composition of the extract and quality indices of the protein fraction found in the defatted meal were analyzed. In the present research project, the study of these issues will be expanded to the use of different oleaginous materials, such as sesame seed, baru almonds and spent coffee. The project will be conducted in three different arms: a) Evaluation of the quality indices of the different protein fractions found in defatted meals, based on analyses that characterize the protein fraction and the functional properties of the protein in greater detail; b) Evaluation of the physical-chemical properties of the vegetable oils obtained from different raw materials using different alcoholic solvents (ethanol or isopropanol, hydrated or not), with emphasis on the behavior of minority compounds of interest (for example, sesamin in sesame oil, and chlorogenic acids in spent coffee oil); c) Study of the liquid-liquid equilibrium as a function of the temperature for systems composed by vegetable oils (sesame seed or baru almond) and solvent. This stage of the project has the aim of evaluating the partial recovery of the alcoholic solvent in the extract, besides studying the fractioning of minority compounds of nutritional interest found in the oils. (AU)

Scientific publications

(19)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

NAVARRO, SANDRA L. B.; CAPELLINI, MARIA C.; ARACAVA, KEILA K.; RODRIGUES, CHRISTIANNE E. C.. Corn germ-bran oils extracted with alcoholic solvents: Extraction yield, oil composition and evaluation of protein solubility of defatted meal. FOOD AND BIOPRODUCTS PROCESSING, v. 100, n. A, p. 185-194, OCT 2016. (14/09446-4)

KAMIMURA, JULIANE A. A. M.; ARACAVA, KEILA K.; RODRIGUES, CHRISTIANNE E. C.. Experimental data and modeling of rice bran oil extraction kinetics using ethanol as solvent. SEPARATION SCIENCE AND TECHNOLOGY, v. 52, n. 12, p. 1921-1928, 2017. (10/16166-7, 14/09446-4, 14/21252-0)

CUEVAS, MAITE S.; CREVELIN, EDUARDO J.; DE MORAES, LUIZ A. B.; OLIVEIRA, ALESSANDRA L.; RODRIGUES, CHRISTIANNE E. C.; MEIRELLES, ANTONIO J. A.. Solubility of commercial octacosanol in organic solvents and their correlation by thermodynamic models at different temperatures. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 110, p. 186-192, JUL 2017. (14/21252-0, 14/09446-4, 15/07370-3, 07/06170-4, 08/56258-8)

OKIYAMA, DAYANE C. G.; NAVARRO, SANDRA L. B.; RODRIGUES, CHRISTIANNE E. C.. Cocoa shell and its compounds: Applications in the food industry. TRENDS IN FOOD SCIENCE & TECHNOLOGY, v. 63, p. 103-112, MAY 2017. (15/03579-5, 14/09446-4)

TODA, TATIANE AKEMI; SAWADA, MIRIAN MEGUMI; RODRIGUES, CHRISTIANNE E. C.. Kinetics of soybean oil extraction using ethanol as solvent: Experimental data and modeling. FOOD AND BIOPRODUCTS PROCESSING, v. 98, p. 1-10, APR 2016. (10/03058-1, 14/09446-4, 09/17855-3, 11/09543-1, 08/56258-8, 13/25142-2)

FLORIDO, PRISCILA M.; LOBO, DEBORAH P. S.; PINTO, CAMILA N.; RODRIGUES, CHRISTIANNE E. C.; GONCALVES, CINTIA B.. Physical properties of systems of interest to the edible oil industry: Viscosities and densities of model systems formed by (triacylglycerol plus fatty acid plus solvent). JOURNAL OF CHEMICAL THERMODYNAMICS, v. 113, p. 198-212, OCT 2017. (12/23203-1, 15/16781-7, 14/21252-0, 14/09446-4, 15/23372-6, 14/09757-0)

NAVARRO, SANDRA L. B.; CAPELLINI, MARIA C.; ARACAVA, KEILA K.; RODRIGUES, CHRISTIANNE E. C.. Corn germ-bran oils extracted with alcoholic solvents: Extraction yield, oil composition and evaluation of protein solubility of defatted meal. FOOD AND BIOPRODUCTS PROCESSING, v. 100, p. 10-pg., 2016-10-01. (14/09446-4)

OKIYAMA, DAYANE C. G.; SOARES, INGRID D.; CUEVAS, MAITE S.; CREVELIN, EDUARDO J.; MORAES, LUIZ A. B.; MELO, MARIZA P.; OLIVEIRA, ALESSANDRA L.; RODRIGUES, CHRISTIANNE E. C.. Pressurized liquid extraction of flavanols and alkaloids from cocoa bean shell using ethanol as solvent. Food Research International, v. 114, p. 20-29, DEC 2018. (14/09446-4, 15/03579-5, 17/20840-4, 14/21252-0, 16/15865-5)

NAVARRO, SANDRA L. B.; RODRIGUES, CHRISTIANNE E. C.. Macadamia Oil Extraction With Alcoholic Solvents: Yield and Composition of Macadamia Oil and Production of Protein Concentrates From Defatted Meal. EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, v. 120, n. 7, JUL 2018. (17/20840-4, 14/09446-4, 14/21252-0)

OKIYAMA, DAYANE C. G.; SOARES, INGRID D.; TODA, TATIANE A.; OLIVEIRA, ALESSANDRA L.; RODRIGUES, CHRISTIANNE E. C.. Effect of the temperature on the kinetics of cocoa bean shell fat extraction using pressurized ethanol and evaluation of the lipid fraction and defatted meal. INDUSTRIAL CROPS AND PRODUCTS, v. 130, p. 96-103, APR 2019. (16/15865-5, 15/03579-5, 14/09446-4, 14/21252-0)

BESSA, LARISSA C. B. A.; FERREIRA, MARCELA C.; RODRIGUES, CHRISTIANNE E. C.; BATISTA, EDUARDO A. C.; MEIRELLES, ANTONIO J. A.. Simulation and process design of continuous countercurrent ethanolic extraction of rice bran oil. Journal of Food Engineering, v. 202, p. 99-113, JUN 2017. (09/54137-1, 08/56258-8, 14/21252-0, 14/09446-4)

CAPELLINI, MARIA C.; GONCALVES, DANIEL; SOARES, INGRID D.; ALMEIDA, CAMILA H.; MARGOTO, CRISTIANE M.; KOSHIMA, CRISTINA C.; RODRIGUES, CHRISTIANNE E. C.. Solvent recovery from systems containing crude sesame seed oil and short-chain alcohols at different temperatures and local pressure. JOURNAL OF CHEMICAL THERMODYNAMICS, v. 156, MAY 2021. (18/13207-6, 18/12713-5, 14/21252-0, 13/13339-6, 14/09446-4)

CAPELLINI, MARIA C.; CHIAVOLONI, LARISSA; GIACOMINI, VANESSA; RODRIGUES, CHRISTIANNE E. C.. Alcoholic extraction of sesame seed cake oil: Influence of the process conditions on the physicochemical characteristics of the oil and defatted meal proteins. Journal of Food Engineering, v. 240, p. 145-152, JAN 2019. (13/13339-6, 14/09446-4, 14/21252-0, 17/20840-4)

CUEVAS, MAITE S.; DE SOUZA, PATRICIA T.; DA COSTA RODRIGUES, CHRISTIANNE E.; MEIRELLES, ANTONIO J. A.. Quantification and Determination of Composition of Steryl Ferulates in Refined Rice Bran Oils Using an UPLC-MS Method. JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, v. 94, n. 3, p. 375-385, MAR 2017. (09/54137-1, 15/07370-3, 08/56258-8, 14/09446-4, 14/21252-0)

SCHARLACK, NAYARA K.; ARACAVA, KEILA K.; RODRIGUES, CHRISTIANNE E. C.. Effect of the type and level of hydration of alcoholic solvents on the simultaneous extraction of oil and chlorogenic acids from sunflower seed press cake. Journal of the Science of Food and Agriculture, v. 97, n. 13, p. 4612-4620, OCT 2017. (14/09446-4, 14/21252-0)

CAPELLINI, MARIA C.; NOVAIS, JULIANA S.; MONTEIRO, RAFAELLA F.; VEIGA, BRUNO Q.; OSIRO, DENISE; RODRIGUES, CHRISTIANNE E. C.. Thermal, structural and functional properties of rice bran defatted with alcoholic solvents. JOURNAL OF CEREAL SCIENCE, v. 95, SEP 2020. (13/13339-6, 14/21252-0, 14/09446-4, 18/12713-5, 17/20840-4)

GONCALVES, CINTIA B.; RODRIGUES, CHRISTIANNE E. C.; MARCON, ELAINE C.; MEIRELLES, ANTONIO J. A.. Deacidification of palm oil by solvent extraction. Separation and Purification Technology, v. 160, p. 106-111, FEB 29 2016. (01/13733-9, 12/23203-1, 14/09446-4, 00/01685-7)

NAVARRO, SANDRA L. B.; RODRIGUES, CHRISTIANNE E. C.. Macadamia oil extraction methods and uses for the defatted meal byproduct. TRENDS IN FOOD SCIENCE & TECHNOLOGY, v. 54, p. 148-154, AUG 2016. (14/09446-4)

CAPELLINI, MARIA C.; GIACOMINI, VANESSA; CUEVAS, MAITE S.; RODRIGUES, CHRISTIANNE E. C.. Rice bran oil extraction using alcoholic solvents: Physicochemical characterization of oil and protein fraction functionality. INDUSTRIAL CROPS AND PRODUCTS, v. 104, p. 133-143, OCT 1 2017. (14/09446-4, 13/13339-6, 14/21252-0, 10/13285-5)