Generation and storage of New Energy: bringing technological development for the country

• Grant number: 17/11986-5
• Support Opportunities: Research Grants - Research Centers in Engineering Program
• Start date: August 01, 2018
• End date: July 31, 2028
• Field of knowledge: Physical Sciences and Mathematics - Chemistry - Physical-Chemistry
• Agreement: BG E&P Brasil (Shell Group)
• Principal Investigator: Ana Flávia Nogueira
• Grantee: Ana Flávia Nogueira
• Host Institution: Instituto de Química (IQ). Universidade Estadual de Campinas (UNICAMP). Campinas , SP, Brazil
• Host Companies: Universidade Estadual de Campinas (UNICAMP). Instituto de Química (IQ); BG E&P Brasil Ltda
• City: Rio de JaneiroCampinas
• Pesquisadores principais:( Atuais ): Edson Roberto Leite ; Ernesto Chaves Pereira de Souza ; Gustavo Doubek ; Hudson Giovani Zanin ; Lucia Helena Mascaro Sales ; Pablo Sebastián Fernández ; Raphael Nagao de Sousa
• Pesquisadores principais:( Anteriores ): Claudia Longo ; Flavio Leandro de Souza
• Associated researchers: Alfeu Joãozinho Sguarezi Filho ; André Luiz Barboza Formiga ; André Sarto Polo ; Arnaldo Naves de Brito ; Caio Costa Oliveira ; Cauê Ribeiro de Oliveira ; Claudia Longo ; Elisabete Inacio Santiago ; Elton Fabiano Sitta ; Fernando Aparecido Sigoli ; Flavio Leandro de Souza ; Francisco das Chagas Marques ; Fritz Cavalcante Huguenin ; Gregório Couto Faria ; Gregory Bregion Daniel ; Helio Fiori de Castro ; Italo Odone Mazali ; Jilian Nei de Freitas ; José Mario de Aquino ; Josimar Ribeiro ; Juliano Alves Bonacin ; Katia Lucchesi Cavalca Dedini ; Lázaro Aurélio Padilha Junior ; Leonardo Morais da Silva ; Lucia Helena Mascaro Sales ; Marco Aurélio Liutheviciene Cordeiro ; Mateus Giesbrecht ; Pablo Sebastián Fernández ; Raphael Nagao de Sousa ; Raphael Soeiro Suppino ; Renato Garcia de Freitas Sobrinho ; René Alfonso Nome Silva ; Tárcio André dos Santos Barros ; Tiago Henrique Machado
• Associated research grant(s): 24/18436-4 - Multi-user equipment approved in grant 17/11986-5: IV+Spectral Response+Quantum Efficiency+PDS, AP.EMU; 24/07429-7 - IECON 2024 - 50th Annual Conference of the IEEE Industrial Electronics Society, AR.EXT; 24/11905-9 - Multi-user equipment approved in grant 17/11986-5: confocal raman microscope, AP.EMU; + associated grants 24/11906-5 - Multi-user Equipment approved in grant 17/11986-5: spectrofluorimeter, AP.EMU; 23/07795-0 - 15th International Conference on Electronic Spectroscopy and Structure, AR.EXT; 19/22419-0 - Japan-Brazil research collaboration for green electronics -Study of non-toxic halide perovskite thin-film solar cells-, AP.R SPRINT; 19/16633-9 - Solar driven organic transformations to enhance hydrogen production, AP.R SPRINT; 19/23181-7 - Multiuser equipment granted in the Project Fapesp 2017/11986-5: interface controler for atomic force microscope, AP.EMU; 19/09838-3 - Multiuser equipments: integrated system for photo electrochemical experiments, AP.EMU; 18/14296-2 - International Conference on Electron Spectroscopy and Structure (ICESS-14), AR.EXT - associated grants
• Associated scholarship(s): 24/07586-5 - Energy generation from the (photo)catalytic contaminants oxidation in different domestic and industrial wastewater, BP.DR; 25/02512-6 - INVESTIGATION OF COBALT HYDROXIDE NANOPARTICLE-BASED ELECTROCATALYSTS FOR THE ELECTROCATALYTIC REDUCTION OF NITRATE TO AMMONIA, BP.IC; 25/00167-0 - Ni alloy/semiconductor composites for green hydrogen production through photoelectrochemical water splitting, BP.PD; + associated scholarships 24/16986-7 - Synthesis of Mixed Metal Oxides for Electrocatalysis of Water and Organic Molecules Oxidation Reactions in Acidic Medium, BP.DR; 24/02127-2 - Innovative high-entropy alloys for electrochemical storage of hydrogen, BP.DR; 24/14118-8 - Investigation of the influence of different metals on high-entropy layered oxides for cathodes for sodium-ion batteries, BP.PD; 24/07435-7 - Fundamental Studies on the Exsolution Mechanism of Platinum NPs from Perovskite Oxides and Their Application in Polyols Electro-oxidation, BP.MS; 23/08460-2 - Exsolution of Iridium Nanoparticles from Perovskite Oxides: searching for More Active and Stable Catalysts for the Production of Green Hydrogen, BP.PD; 23/10395-4 - Applying quantum dots passivation towards high-stability perovskite solar cells, BP.PD; 23/09924-2 - Study of electronic levels of charge carrier layers for use in perovskite solar cells, BP.MS; 23/02033-5 - Exsolution of platinum nanoparticles from perovskite oxides: sustainable conversion of glycerol and the production of green hydrogen, BP.DR; 22/16614-7 - Stability and formation dynamics of 2D/3D perovskites interface investigated by in situ techniques, BP.PD; 22/04724-2 - Ligand design towards CO2conversion by coordination compounds, BP.PD; 21/05853-8 - Gas diffusion photoelectrodes with copper tungstates for application on photoassisted CO2 reduction reaction, BP.DD; 21/07459-5 - Control of electronic properties of columnar hematite nanostructure by double transition elements insertion for photoelectrocatalitic water splitting, BP.PD; 21/02678-0 - Fundamental studies in the field of electrochemistry at the level of single nanoparticles using synchrotron-based techniques, BP.DR; 20/14451-8 - From small to large-area: a systematic study for the scale-up of perovskite solar cells, BP.PD; 20/07955-0 - Development and characterization of microfluidic electrochemical cells for measurements of Bragg coherent diffraction imaging in situ, BP.IC; 20/04406-5 - Perovskite solar cells from easy, cheap and green sources: a synergistic approach for the synthesis of new organic hole transport materials and the use of more environmental-friendly solvents, BP.DD; 20/04822-9 - Breaking matter complexity with resonant inelastic x-ray scattering: the role of different conformers and their respective nuclear dynamics, BP.PD; 19/13888-6 - Fundamental studies of the electrode-solution interface in relevant systems in (electro)catalysis, BP.MS; 19/00305-2 - Development of p-block adatom-modified platinum electrocatalysts for the electrochemical conversion of glycerol in alkaline medium, BP.DR; 19/25765-6 - In situ experiments with synchrotron based SAXS and WAXS to probe reactions and formation mechanisms of trending (nanostructured) lead halide materials, BP.DR; 19/17170-2 - Stability of perovskite films: a comparison between 2D-stabilized and rubidium-based perovskites studied by imaging and spectroscopic techniques, BP.PD; 19/08257-7 - Synthesis and characterization of hole transport materials for perovskite solar cell, BP.MS; 19/01470-7 - Engineering Interfaces on Hematite Electrodes for Sunlight Assisted Water Oxidation., BP.PD; 18/14699-0 - Bismuth and antimony based perovskite solar cells, BP.IC - associated scholarships
• FAPESP publication: https://media.fapesp.br/bv/uploads/pdfs/fapesp_uk_zyv6Z1q_158_159.pdf

Abstract

The project "New Energy Generation and Storage: bringing technological development to the country" encompasses the research and extension activities of three CINE phase 2 programs from 2023 to 2028: Energy Generation (EG), Advanced Energy Energy (Advanced Energy Storage, AES) and Green Hydrogen Generation (GH2). The project is part of CINE's mission, which is the development of national technologies in the area of new energies, focusing on the energy transition environment the country is going through, with the commitment to an economy with low carbon emissions. All projects have as their objective a careful look at the country's electricity matrix, which is currently 83% renewable. The advance mainly in the expansion of photovoltaic energy that recently surpassed wind energy and both should assume the leading role in clean electricity generation in the world in 10-15 years, which justifies the creation of the EG program. The GH2 program brings to CINE the agenda for the generation of green hydrogen, which has become one of the main energy transport vectors in the next 10-15 years. Electric mobility and stationary energy storage are guidelines of the AES program brought about by recent discussions on how Brazil and the world will deal with the transport of cargo and passengers, as well as incorporating a greater share of wind and photovoltaic energy in the electrical grid. All programs cover fundamental studies of the technologies to be approached, with a focus on in situ and in operando characterizations using advanced techniques (as is the case of studies that are already being carried out in collaboration with Sirius in Campinas and other laboratories that use synchrotron radiation). Also planned are the development and improvement of functional materials, such as catalysts, photocatalysts, membranes, support substrates, etc., with a focus on cost reduction, use of local inputs and production, reduction in the use of rare metals and expansion of the use of carbon and derivatives, increased generation efficiency and stability. The expansion of technologies to prototype scale will be carried out in several projects, such as perovskite solar cells, PEM electrolysers, photoelectrochemical cells, batteries and supercapacitors. Part of this upscaling has already started in CINE phase 1 and should be promoted more strongly in phase 2. This will allow many projects that are at TRL 3 technological goal level to move to TRL 4 or 5 in the coming years. (AU)

Scientific publications

(241)

(References retrieved automatically from Web of Science and SciELO through information on FAPESP grants and their corresponding numbers as mentioned in the publications by the authors)

THEODORA W. VON ZUBEN; DANIEL E. B. MOREIRA; RAFAEL L. GERMSCHEIDT; RAFAEL G. YOSHIMURA; DANIEL S. DORRETTO; ANA B. S. DE ARAUJO; AIRTON G. SALLES JR.; JULIANO A. BONACIN. Is Hydrogen Indispensable for a Sustainable World? A Review of H2 Applications and Perspectives for the Next Years. Journal of the Brazilian Chemical Society, v. 33, n. 8, p. 824-843, 2022-06-15. (19/20688-3, 17/23960-0, 21/05976-2, 18/25092-9, 13/22127-2, 17/11986-5)

ROGER GONÇALVES; ERNESTO C. PEREIRA. Chemometric Evaluation of Poly(3-hexylthiophene) Electrochemical Aging Path as a Function of Electrochemical Synthesis Variables. Journal of the Brazilian Chemical Society, v. 33, n. 7, p. 762-771, 2022-06-17. (17/06536-0, 17/11986-5, 11/10897-2, 14/50249-8, 15/17141-1)

DE HOLANDA, MATHEUS S.; SZOSTAK, RODRIGO; MARCHEZI, PAULO E.; DUARTE, LUIS G. T. A.; GERMINO, JOSE C.; ATVARS, TERESA D. Z.; NOGUEIRA, ANA F.. In Situ 2D Perovskite Formation and the Impact of the 2D/3D Structures on Performance and Stability of Perovskite Solar Cells. SOLAR RRL, v. 3, n. 9, SI, JULY 2019. (13/16245-2, 17/11986-5, 17/12582-5)

MOTA, ISABELA CUSTODIO; SILVA SANTOS, BIANCA PEDROSO; PEREIRA DOS SANTOS, RAPHAEL ERTOLA; GUEDES, LUISA BANAR; SOARES, IGOR TENORIO; RUBIO ARIAS, JOSE JONATHAN; DE ARAUJO, FRANCINEIDE LOPES; NOGUEIRA, ANA FLAVIA; VIEIRA MARQUES, MARIA DE FATIMA. Influence of reaction time on properties of regioregular poly(3-hexylthiophene) by the Grignard metathesis polymerization. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, JUN 2021. (17/11986-5)

CALDERON-CARDENAS, ALFREDO; PAREDES-SALAZAR, ENRIQUE A.; MUJICA-MARTINEZ, CESAR A.; NAGAO, RAPHAEL; VARELA, HAMILTON. Thorough Analysis of the Effect of Temperature on the Electro-Oxidation of Formic Acid. Journal of Physical Chemistry C, v. 124, n. 44, SI, p. 24259-24270, NOV 5 2020. (13/16930-7, 16/01817-9, 17/11986-5)

BONATO, LUIZ G.; MORAL, RAPHAEL F.; NAGAMINE, GABRIEL; ALO, ARTHUR; GERMINO, JOSE C.; DA SILVA, DOUGLAS S.; ALMEIDA, DIOGO B.; ZAGONEL, LUIZ F.; GALEMBECK, FERNANDO; PADILHA, LAZARO A.; et al. Revealing the Role of Tin(IV) Halides in the Anisotropic Growth of CsPbX3 Perovskite Nanoplates. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, MAY 2020. (14/50906-9, 18/15574-6, 17/11986-5, 16/02268-9, 13/16911-2)

RAPHAEL F. MORAL; ALDEN B. HERMSDORFF; PAULO E. MARCHEZI; JOSÉ C. GERMINO; LUIZ G. BONATO; FRANCINEIDE L. DE ARAÚJO; ANA F. NOGUEIRA. Addition of N-(2-Aminoethyl)naphthalimide and Mercaptopropionic Acid to Increase the Stability of CsFAMA Perovskite Solar Cells. Journal of the Brazilian Chemical Society, v. 33, n. 8, p. 997-1007, 2022-06-15. (17/11986-5, 19/25765-6, 21/13262-0, 20/14451-8)

OZORIO, MAILDE S.; OLIVEIRA, WILLIAN X. C.; SILVEIRA, JULIAN F. R. V.; NOGUEIRA, ANA FLAVIA; DA SILVA, JUAREZ L. F.. Novel zero-dimensional lead-free bismuth based perovskites: from synthesis to structural and optoelectronic characterization. MATERIALS ADVANCES, v. 1, n. 9, p. 3439-3448, DEC 1 2020. (18/21401-7, 17/11631-2, 17/11986-5)

CARMINATI, SAULO AMARAL; NOGUEIRA, ANA FLAVIA. p SnO2 as thin conformal layer over BiVO4 surface for enhanced charge carrier separation towards O2 evolution from water oxidation. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, v. 47, n. 8, p. 5211-5219, JAN 26 2022. (17/11986-5, 16/23178-8, 15/23775-3)

MARQUES, ADRIANO S.; FARIA, ROBERTO M.; FREITAS, JILIAN N.; NOGUEIRA, ANA F.. Low-Temperature Blade-Coated Perovskite Solar Cells. Industrial & Engineering Chemistry Research, v. 60, n. 19, p. 7145-7154, MAY 19 2021. (17/12582-5, 17/11986-5)

SANTOS, BIANCA PEDROSO S.; CORREA, ROGER S.; VEIGA, AMANDA G.; PEAN, V, EMMANUEL; BORGES, BRUNO G. A. L.; ARAUJO, FRANCINEIDEL; RIBEIRO, ARTHUR C.; FURTADO, JOSE G. M.; DAVIES, MATTHEW L.; NOGUEIRA, ANA F.; et al. Statistical and block conjugated polymers for bulk heterojunction solar cells: Molecular orientation, charge transfer dynamics and device performance. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, v. 270, AUG 2021. (17/11986-5)

NAKAJIMA, KIMIKO; SOUZA, FLAVIO L.; FREITAS, ANDRE L. M.; THRON, ANDREW; CASTRO, RICARDO H. R.. Improving Thermodynamic Stability of nano-LiMn2O4 for Li-Ion Battery Cathode. CHEMISTRY OF MATERIALS, v. 33, n. 11, p. 3915-3925, JUN 8 2021. (17/11986-5)

HIGGINS, MARISSA; ELY, FERNANDO; NOME, RENATA C.; NOME, RENE A.; DOS SANTOS, DIEGO P.; CHOI, HYUNJOO; NAM, SEUNGJIN; QUEVEDO-LOPEZ, MANUEL. Enhanced reproducibility of planar perovskite solar cells by fullerene doping with silver nanoparticles. Journal of Applied Physics, v. 124, n. 6, AUG 14 2018. (17/11986-5, 14/50632-6, 15/14183-5)

DOS SANTOS, CAIO G. P.; MACHADO, EDUARDO G.; KISS, ISTVAN Z.; NAGAO, RAPHAEL. Investigation of the Oscillatory Electrodissolution of the Nickel-Iron Alloy. Journal of Physical Chemistry C, v. 123, n. 39, p. 24087-24094, OCT 3 2019. (18/21619-2, 16/01817-9, 17/11986-5)

OLIVEIRA, GUILHERME H.; GALANTE, MIGUEL T.; MARTINS, THALYTA T.; DOS SANTOS, LEONARDO F. L. S.; ELY, FERNANDO; LONGO, CLAUDIA; GONCALVES, RENATO V.; MUNIZ, SERGIO R.; NOME, RENE A.. Real time single TiO2 nanoparticle monitoring of the photodegradation of methylene blue. Solar Energy, v. 190, p. 239-245, SEP 15 2019. (16/23430-9, 13/07276-1, 17/11986-5)

MENEZES, LAURA; PARMA, EDUARDO; MACHADO, EDUARDO G.; NAGAO, RAPHAEL. Quasiperiodic behavior in the electrodeposition of Cu/Sn multilayers: extraction of activation energies and wavelet analysis. Physical Chemistry Chemical Physics, v. 21, n. 37, p. 21057-21063, OCT 7 2019. (16/01817-9, 17/11986-5)

COUTINHO, NATALIA F.; CUCATTI, SILVIA; MERLO, RAFAEL B.; SILVA FILHO, JOSE MARIA C.; BORRERO VILLEGAS, NELSON F.; ALVAREZ, FERNANDO; NOGUEIRA, ANA F.; MARQUES, FRANCISCO C.. The Thermomechanical Properties of Thermally Evaporated Bismuth Triiodide Thin Films. SCIENTIFIC REPORTS, v. 9, AUG 13 2019. (12/10127-5, 17/11986-5)

OLIVEIRA, GUILHERME H.; NOME, RENE A.. Integrating ultrafast and stochastic dynamics studies of Brownian motion in molecular systems and colloidal particles. CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, v. 44, p. 208-219, DEC 2019. (19/00290-5, 17/11986-5, 16/23430-9)

COSTA, MAGNO BARCELOS; LUCAS, FRANCISCO W. S.; MASCARO, LUCIA HELENA. Electrodeposition Conditions Effect Sb2Se3 Thin-Film Properties. CHEMELECTROCHEM, v. 6, n. 11, p. 2937-2944, JUN 3 2019. (17/11986-5, 17/21365-8, 18/16401-8, 18/03156-5, 13/07296-2)

GALUPPO, CAROLINA; ALVARENGA, JAQUELINE; QUEIROZ, ADRIANA C.; MESSIAS, IGOR; NAGAO, RAPHAEL; ABBEHAUSEN, CAMILLA. The electrosynthesis of gold(I) complexes: A clean, one-pot method. Electrochemistry Communications, v. 110, JAN 2020. (17/12719-0, 16/01817-9, 17/11986-5)

DA SILVA, JEANN CARLOS; DE ARAUJO, FRANCINEIDE LOPES; SZOSTAK, RODRIGO; MARCHEZI, PAULO ERNESTO; MORAL, RAPHAEL FERNANDO; DE FREITAS, JILIAN NEI; NOGUEIRA, ANA FLAVIA. Effect of the incorporation of poly(ethylene oxide) copolymer on the stability of perovskite solar cells. JOURNAL OF MATERIALS CHEMISTRY C, v. 8, n. 28, p. 9697-9706, JUL 28 2020. (19/25765-6, 17/11986-5, 17/12582-5)

MELLE, GABRIEL; DE SOUZA, MATHEUS B. C.; SANTIAGO, PATRICIA V. B.; CORRADINI, PATRICIA GON; MASCARO, LUCIA HELENA; FERNANDEZ, PABLO S.; SITTA, ELTON. Glycerol electro-oxidation at Pt in alkaline media: influence of mass transport and cations. Electrochimica Acta, v. 398, DEC 1 2021. (19/00305-2, 14/50249-8, 17/11986-5, 13/07296-2, 18/20952-0)

ALMORA, OSBEL; BARAN, DERYA; BAZAN, GUILLERMO C.; BERGER, CHRISTIAN; CABRERA, I, CARLOS; CATCHPOLE, KYLIE R.; ERTEN-ELA, SULE; GUO, FEI; HAUCH, JENS; HO-BAILLIE, ANITA W. Y.; et al. Device Performance of Emerging Photovoltaic Materials (Version 2). ADVANCED ENERGY MATERIALS, v. 11, n. 48, NOV 2021. (17/11986-5)

POCHAPSKI, DANIEL JOSE; DOS SANTOS, CAIO CARVALHO; LEITE, GABRIEL WOSIAK; PULCINELLI, SANDRA HELENA; SANTILLI, CELSO VALENTIM. Zeta Potential and Colloidal Stability Predictions for Inorganic Nanoparticle Dispersions: Effects of Experimental Conditions and Electrokinetic Models on the Interpretation of Results. Langmuir, v. 37, n. 45, p. 13379-13389, NOV 16 2021. (14/50249-8, 14/50948-3, 18/24383-0, 17/11986-5)

GERMINO, JOSE CARLOS; SZOSTAK, RODRIGO; MOTTI, SILVIA G.; MORAL, RAPHAEL F.; MARCHEZI, PAULO E.; SELEGHINI, HEITOR S.; BONATO, LUIZ G.; DE ARAUJO, FRANCINEIDE LOPES; ATVARS, TERESA D. Z.; HERZ, LAURA M.; et al. Postpassivation of Multication Perovskite with Rubidium Butyrate. ACS PHOTONICS, v. 7, n. 8, p. 2282-2291, AUG 19 2020. (18/25801-0, 17/11986-5, 19/25765-6, 17/12582-5)

LIMA, CARLOS C.; RODRIGUES, MARTA V. F.; NETO, ANTONIO F. M.; ZANATA, CINTHIA R.; PIRES, CLEO T. G. V. M. T.; COSTA, LUELC S.; SOLLA-GULLON, JOSE; FERNANDEZ, PABLO S.. Highly active Ag/C nanoparticles containing ultra-low quantities of sub-surface Pt for the electrooxidation of glycerol in alkaline media. APPLIED CATALYSIS B-ENVIRONMENTAL, v. 279, DEC 15 2020. (16/01365-0, 17/11986-5, 18/20952-0)

MOREIRA, AILTON JOSE; LEMOS, SHERLAN; COELHO, DYOVANI; MASCARO, LUCIA; FRESCHI, GIAN; PEREIRA, ERNESTO. UV-Vis spectrophotometry coupled to chemometric analysis for the performance evaluation of atrazine photolysis and photocatalysis. Environmental Science and Pollution Research, NOV 2021. (14/50249-8, 17/11986-5, 13/07296-2)

DE MEDEIROS, JESSYCA FERREIRA; GALANTE, MIGUEL TAYAR; BERTAZZOLI, RODNEI; DOS SANTOS, CAIO GUILHERME PEREIRA; LONGO, CLAUDIA. Solar-Driven Photoreactor for Water Remediation Based on n-Type TiO2 and p-Type Ag/AgBiW2O8/Bi2WO6 Light-Responsive Air-Fed Gas Diffusion Electrodes. ACS ES&T WATER, v. 2, n. 6, p. 12-pg., 2022-06-10. (17/11986-5, 19/09838-3)

KODALLE, TIM; MORAL, RAPHAEL F.; SCALON, LUCAS; SZOSTAK, RODRIGO; ABDELSAMIE, MAGED; MARCHEZI, PAULO E.; NOGUEIRA, ANA F.; SUTTER-FELLA, CAROLIN M.. Revealing the Transient Formation Dynamics and Optoelectronic Properties of 2D Ruddlesden-Popper Phases on 3D Perovskites. ADVANCED ENERGY MATERIALS, v. N/A, p. 14-pg., 2022-06-30. (21/01357-6, 17/11986-5, 19/25765-6, 17/12582-5)

THOMAZ, KELLY T. C.; BEDIN, KAREN C.; RODRIGUEZ-GUTIERREZ, INGRID; VERISSIMO, NATHALIA C.; BETTINI, JEFFERSON; SOUZA, FLAVIO L.. Interfacial engineering of hematite photoanodes toward high water splitting performance. MATERIALS TODAY ENERGY, v. 37, p. 11-pg., 2023-10-01. (17/11986-5, 17/02317-2, 21/07459-5, 19/06654-9)

PIRES, FABIO A.; DOS SANTOS, GABRIEL T.; BETTINI, JEFFERSON; COSTA, CARLOS A. R.; GONCALVES, RENATO V.; CASTRO, RICARDO H. R.; SOUZA, FLAVIO L.. Selective placement of modifiers on hematite thin films for solar water splitting. SUSTAINABLE ENERGY & FUELS, v. N/A, p. 13-pg., 2023-09-07. (17/11986-5, 17/02317-2, 22/04150-6, 21/04967-0)

PILONETTO, LUIS FELIPE; STACIAKI, FELIPE; NOBREGA, ERYKA; CARNEIRO-NETO, EVALDO B.; DA SILVA, JEYSE; PEREIRA, ERNESTO. Mitigating the capacity loss by crossover transport in vanadium redox flow battery: A chemometric efficient strategy proposed using finite element method simulation. CHEMICAL ENGINEERING JOURNAL, v. 474, p. 8-pg., 2023-10-15. (17/11986-5, 21/03592-2, 19/27029-5, 21/11630-1, 19/11095-9, 22/05254-0, 13/07296-2)

PIRES, FABIO A.; DOS SANTOS, GABRIEL T.; BETTINI, JEFFERSON; COSTA, CARLOS A. R.; GONCALVES, RENATO V.; CASTRO, RICARDO H. R.; SOUZA, FLAVIO L.. Selective placement of modifiers on hematite thin films for solar water splitting. SUSTAINABLE ENERGY & FUELS, v. 7, n. 20, p. 14-pg., 2023-10-10. (17/11986-5, 17/02317-2, 22/04150-6, 21/04967-0)

BLASKIEVICZ, SIRLON F.; TEIXEIRA, IVO FREITAS; MASCARO, LUCIA HELENA; DE BRITO, JULIANA FERREIRA. Direct Z-scheme among Niobium Pentoxide and Poly(heptazine imide) for NH3 Photoelectrosynthesis under Ambient Conditions. CHEMCATCHEM, v. N/A, p. 10-pg., 2023-01-26. (13/07296-2, 18/02950-0, 17/11986-5)

VIANA, GUSTAVO ALEXANDRE; DA SILVA, DOUGLAS SOARES; LANDERS, RICHARD; DE FREITAS, JILIAN NEI; VILLALVA, MARCELO GRADELLA; MARQUES, FRANCISCO DAS CHAGAS. Desorption of chemical species during thermal reduction of graphene oxide films. SURFACE & COATINGS TECHNOLOGY, v. 463, p. 10-pg., 2023-04-21. (17/11986-5)

SALOMAO, ARTHUR CORRADO; DOS SANTOS ARAUJO, MILENY; DOS SANTOS, HUGO LEANDRO SOUSA; MEDINA, MARINA; MASCARO, LUCIA HELENA; ANDRADE JUNIOR, MARCOS ANTONIO SANTANA. owards Highly Efficient Chalcopyrite Photocathodes for Water Splitting: The Use of Cocatalysts beyond P. CHEMSUSCHEM, v. 14, n. 21, SEP 2021. (19/26860-2, 17/15144-9, 13/07296-2, 20/09000-7, 17/12794-2, 17/11986-5, 14/50249-8)

ANDRADE, RENATO N. DE; PERINI, NICKSON; VIEIRA, JOSE LUCAS; GALLO, JEAN MARCEL R.; SITTA, ELTON. Glycerol electrooxidation catalyzed by Pt-Sb supported in periodic mesoporous carbon CMK-3 and CMK-5. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 896, SEP 1 2021. (20/04109-0, 13/07296-2, 16/02128-2, 17/11986-5)

DE BRITO, JULIANA FERREIRA; MASCARO, LUCIA HELENA. Enhancement of photocurrent response for self-ordered Nb2O5 nanotubes synthesized at room temperature. Journal of Materials Science, v. 56, n. 3, p. 2088-2102, JAN 2021. (14/50249-8, 18/02950-0, 17/11986-5, 13/07296-2, 18/16401-8)

SANTIAGO, PATRICIA V. B.; RAJU, SWATHI P.; AKKIRAJU, KARTHIK; VICENTE, RAFAEL A.; DA SILVA, MARIANE A.; YUAN, SHUAI; ZANCHET, DANIELA; SHAO-HORN, YANG; FERNANDEZ, PABLO S.. Perovskite Oxides as an Opportunity to Systematically Study the Electrooxidation of Alcohols and Polyols on Materials Based on Abundant Elements: Learning from the Experience Using Pure Metals and Metallic Oxides in Electrocatalysis. ACS APPLIED ENERGY MATERIALS, v. 6, n. 13, p. 27-pg., 2023-06-23. (17/11986-5, 20/04431-0)

GONZAGA, ISABELLE M. D.; ALMEIDA, CAIO V. S.; MASCARO, LUCIA H.. A Critical Review of Photo-Based Advanced Oxidation Processes to Pharmaceutical Degradation. CATALYSTS, v. 13, n. 2, p. 34-pg., 2023-02-01. (17/11986-5, 20/15211-0, 13/07296-2, 21/14693-4)

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DE SOUZA, MATHEUS B. C.; GUIMA, KATIA-EMIKO; FERNANDEZ, PABLO S.; MARTINS, CAUE A.. Glycerol Is Converted into Energy and Carbonyl Compounds in a 3D-Printed Microfluidic Fuel Cell: In Situ and In Operando Bi-Modified Pt Anodes. ACS APPLIED MATERIALS & INTERFACES, v. 14, n. 22, p. 9-pg., 2022-06-08. (18/20952-0, 17/11986-5)

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DE ARAUJO, MOISES A.; COSTA, MAGNO B.; MASCARO, LUCIA H.. Improved Photoelectrochemical Hydrogen Gas Generation on Sb2S3 Films Modified with an Earth-Abundant MoSx Co-Catalyst. ACS APPLIED ENERGY MATERIALS, v. 5, n. 1, p. 13-pg., 2022-01-13. (17/21365-8, 17/11986-5, 13/07296-2, 16/12681-0)

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DE HOLANDA, MATHEUS S.; MORAL, RAPHAEL F.; MARCHEZI, PAULO E.; MARQUES, FRANCISCO C.; NOGUEIRA, ANA FLAVIA. Layered metal halide perovskite solar cells: A review from structure-properties perspective towards maximization of their performance and stability. ECOMAT, JUL 2021. (17/11986-5, 19/25765-6)

GRANAS, O.; MOCELLIN, A.; CARDOSO, E. S.; BURMEISTER, F.; CALEMAN, C.; BJORNEHOLM, O.; NAVES DE BRITO, A.. Femtosecond fragmentation of CS2 after sulfur 1s ionization: interplay between Auger cascade decay, charge delocalization, and nuclear motion. JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, v. 53, n. 24, DEC 28 2020. (17/11986-5)

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COELHO, DYOVANI; GAUDENCIO, JOAO PEDRO R. S.; CARMINATI, SAULO A.; RIBEIRO, FRANCISCO W. P.; NOGUEIRA, ANA F.; MASCARO, LUCIA H.. Bi electrodeposition on WO3 photoanode to improve the photoactivity of the WO3/BiVO4 heterostructure to water splitting. CHEMICAL ENGINEERING JOURNAL, v. 399, NOV 1 2020. (14/06704-2, 17/11986-5, 18/16401-8, 13/07296-2)

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SOUZA, JR., JOAO B.; SOUZA, FLAVIO L.; VAYSSIERES, LIONEL; VARGHESE, OOMMAN K.. On the relevance of understanding and controlling the locations of dopants in hematite photoanodes for low-cost water splitting. Applied Physics Letters, v. 119, n. 20, NOV 15 2021. (17/02317-2, 17/11986-5)

SANTOS, HUGO L. S.; CORRADINI, PATRICIA G.; MEDINA, MARINA; DIAS, JEFERSON A.; MASCARO, LUCIA H.. NiMo-NiCu Inexpensive Composite with High Activity for Hydrogen Evolution Reaction. ACS APPLIED MATERIALS & INTERFACES, v. 12, n. 15, p. 17492-17501, APR 15 2020. (17/12794-2, 17/11986-5, 18/16401-8, 13/07296-2)

PINTO, MARIA R.; PEREIRA, GUILHERME B.; QUEIROZ, ADRIANA C.; NAGAO, RAPHAEL. Influence of the Ligands in Cu(II) Complexes on the Oscillatory Electrodeposition of Cu/Cu2O. Journal of Physical Chemistry C, v. 124, n. 23, p. 12559-12568, JUN 11 2020. (19/08244-2, 16/01817-9, 17/11986-5)

COSTA, MAGNO BARCELOS; LUCAS, FRANCISCO W. S.; MASCARO, LUCIA HELENA. Improvement of electrodeposited Sb(2)Se(3)thin film photoelectroactivity by cobalt grain boundary modification. JOURNAL OF MATERIALS CHEMISTRY A, v. 8, n. 27, p. 13742-13753, JUL 21 2020. (17/11986-5, 18/16401-8, 18/03156-5, 17/21365-8)

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DA SILVA FILHO, JOSE MARIA C.; GONCALVES, AGNALDO D.; MARQUES, FRANCISCO C.; DE FREITAS, JILIAN N.. A Review on the Development of Metal Grids for the Upscaling of Perovskite Solar Cells and Modules. SOLAR RRL, DEC 2021. (17/11986-5)

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AGREN, HANS; BJORNEHOLM, OLLE; OHRWALL, GUNNAR; CARRAVETTA, VINCENZO; DE BRITO, ARNALDO NAVES. Ethanol in Aqueous Solution Studied by Microjet Photoelectron Spectroscopy and Theory. ACCOUNTS OF CHEMICAL RESEARCH, v. 55, n. 21, p. 8-pg., 2022-10-17. (17/11986-5)

GALANTE, MIGUEL T.; SANTIAGO, PATRICIA V. B.; YUKUHIRO, VICTOR Y.; SILVA, LEONARDO A.; DOS REIS, NATALIA A.; PIRES, CLEO T. G. V. M. T.; MACEDO, NADIA G.; COSTA, LUELC S.; FERNANDEZ, PABLO S.; LONGO, CLAUDIA. Aminopolysiloxane as Cu2O Photocathode Overlayer: Photocorrosion Inhibitor and Low Overpotential CO2-to-formate Selectivity Promoter. CHEMCATCHEM, v. 13, n. 3, DEC 2020. (18/20952-0, 17/11986-5)

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COSTA, MAGNO B.; LUCAS, FRANCISCO W. S.; MEDINA, MARINA; MASCARO, LUCIA H.. All-Electrochemically Grown Sb2Se3/a-MoSx Photocathodes for Hydrogen Production: The Effect of the MoSx Layer on the Surface Recombination and Photocorrosion of Sb2Se3 Films. ACS APPLIED ENERGY MATERIALS, v. 3, n. 10, p. 9799-9808, OCT 26 2020. (17/12794-2, 12/10947-2, 17/11986-5, 17/21365-8, 13/07296-2, 18/16401-8)

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MACHADO, EDUARDO G.; MARCHEZI, PAULO E.; THEREZIO, ERALCI M.; GERMINO, JOSE CARLOS; SZOSTAK, RODRIGO; DE BRITO, CAIQUE S.; GOBATO, YARA G.; PEREIRA, ERNESTO C.; TONEY, MICHAEL F.; NAGAO, RAPHAEL; et al. Light-induced halide segregation in perovskites with wrinkled morphology. JOURNAL OF ENERGY CHEMISTRY, v. 71, p. 6-pg., 2022-04-19. (17/11986-5, 13/07296-2, 17/00089-2, 19/23488-5, 14/50249-8, 16/01817-9, 17/12582-5)

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DA SILVA, KALINE NASCIMENTO; SITTA, ELTON. scillatory dynamics during the methanol electrooxidation reaction on Pt(111. Physical Chemistry Chemical Physics, v. 23, n. 39, AUG 2021. (17/11986-5, 13/07296-2)

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COELHO, DYOVANI; GAUDENCIOA, JOAO PEDRO R. S.; MASCARO, LUCIA H.. Boosting the Photocurrent of the WO3/BiVO4 Heterojunction by Photoelectrodeposition of the Oxy-Hydroxide-Phosphates Based on Co, Fe, or Ni. Journal of the Brazilian Chemical Society, v. 33, n. 8, p. 10-pg., 2022-08-01. (13/07296-2, 17/11986-5, 21/08614-4)

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SANTIAGO, PATRICIA V. B.; LIMA, CARLOS C.; BOTT-NETO, JOSE L.; FERNANDEZ, PABLO S.; ANGELUCCI, CAMILO A.; SOUZA-GARCIA, JANAINA. Perovskite oxides as electrocatalyst for glycerol oxidation. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, v. 896, SEP 1 2021. (18/20952-0, 18/10292-2, 19/07449-0, 16/01365-0, 17/11986-5, 18/06677-6)

GONCALVESA, ROGER; PEREIRA, ERNESTO C.. Chemometric Evaluation of Poly(3-hexylthiophene) Electrochemical Aging Path as a Function of Electrochemical Synthesis Variables. Journal of the Brazilian Chemical Society, v. 33, n. 8, p. 10-pg., 2022-08-01. (15/17141-1, 17/06536-0, 11/10897-2, 13/07296-2, 14/50249-8, 17/11986-5)

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PERINI, NICKSON; HESSEL, CRISTIAN; BOTT-NETO, JOSE L.; PIRES, CLEO T. G. V. M. T.; FERNANDEZ, PABLO S.; SITTA, ELTON. Photoelectrochemical oxidation of glycerol on hematite: thermal effects, in situ FTIR and long-term HPLC product analysis. Journal of Solid State Electrochemistry, v. 25, n. 3, p. 1101-1110, MAR 2021. (17/11986-5, 13/07296-2, 18/20952-0, 16/01365-0, 19/07449-0)

EDUARDO PARMA; LAURA MENEZES; SIDNEI A. BALDIN; RAPHAEL NAGAO. Desenvolvimento de software e interface para o controle por retroalimentação atrasada em sistemas eletroquímicos. Química Nova, v. 44, n. 6, p. 755-759, 2021-08-11. (19/22202-0, 17/11986-5, 16/01817-9, 18/21619-2)

SILVA SANTOS, BIANCA PEDROSO; LIMA, ALLAN BASTOS; DE ARAUJO, FRANCINEIDE LOPES; MOTA, ISABELA CUSTODIO; RIBEIRO, ARTHUR DE CASTRO; NOGUEIRA, ANA FLAVIA; DE MELO FURTADO, JOSE GERALDO; GARCIA FILHO, FABIO DA COSTA; VIEIRA MARQUES, MARIA DE FATIMA; MONTEIRO, SERGIO NEVES. Synthesis of novel low bandgap random and block terpolymers with improved performance in organic solar cells. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, v. 10, p. 51-65, JAN-FEB 2021. (17/11986-5)

MOREIRA, AILTON J.; COELHO, DYOVANI; DIAS, JEFERSON A.; MASCARO, LUCIA H.; FRESCHI, GIAN P. G.; MASTELARO, VALMOR R.; PEREIRA, ERNESTO C.. Phase control and optimization of photocatalytical properties of samarium doped TiO2 synthesized by coupled ultraviolet and microwave radiations. Journal of Alloys and Compounds, v. 905, p. 14-pg., 2022-02-16. (14/50249-8, 13/07296-2, 17/11986-5)

WOSIAK, GABRIEL; SENA, STHEFANY S.; CARNEIRO-NETO, EVALDO B.; LOPES, MAURO C.; PEREIRA, ERNESTO; DA SILVA, JEYSE. Investigation of the influence of the void fraction on the energy consumption of a vertical electrolyser under natural convection. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, v. 10, n. 3, p. 7-pg., 2022-03-31. (14/50249-8, 21/03592-2, 17/11986-5, 19/27029-5, 13/07296-2, 18/24383-0)

YOSHIMURA, RAFAEL G.; DE B. FERRAZ, THIAGO V.; ZAMBIAZI, PRISCILLA J.; BONACIN, JULIANO A.. Co-Prussian blue analogue supported on graphene-based materials as an electrocatalyst for OER at neutral pH. ENERGY ADVANCES, v. 3, n. 2, p. 9-pg., 2023-12-26. (17/11986-5, 21/05976-2)

ZANATTA, A. R.; OLIVEIRA JR, M. H.; MARQUES, F. C.. Raman scattering spectroscopy of micrometer-sized carbon serpentines. Materials Chemistry and Physics, v. 319, p. 6-pg., 2024-04-18. (17/11986-5)

COSTA, MAGNO B.; DE ARAUJO, MOISES A.; TINOCO, MARCOS V. DE LIMA; DE BRITO, JULIANA F.; MASCARO, LUCIA H.. Current trending and beyond for solar-driven water splitting reaction on WO3 photoanodes. JOURNAL OF ENERGY CHEMISTRY, v. 73, p. 26-pg., 2022-07-05. (14/50249-8, 17/11986-5, 18/16401-8, 17/21365-8, 16/12681-0, 13/07296-2, 18/02950-0, 19/22131-6)

DE OLIVEIRA, CRISTIANE; RENDA, CARMEM G.; MOREIRA, AILTON J.; PEREIRA, ERNESTO C.; FRESCHI, GIAN P. G.; BERTHOLDO, ROBERTO. Evaluation of a graphitic porous carbon modified with iron oxides for atrazine environmental remediation in water by adsorption. Environmental Research, v. 219, p. 12-pg., 2022-12-20. (16/20609-8, 13/07296-2, 17/11986-5)

DA SILVA FILHO, JOSE MARIA CLEMENTE; BORRERO, NELSON FABIAN VILLEGAS; DE MORAIS, ANDREIA; DE FREITAS, JILIAN NEI; MARQUES, FRANCISCO DAS CHAGAS. Lead iodide thin films deposited by sputtering: The effect of deposition temperature on the optical and structural properties. NEXT ENERGY, v. 6, p. 8-pg., 2025-01-01. (17/11986-5)

COSTA, MAGNO B.; DE ARAUJO, MOISES A.; PUIGDOLLERS, JOAQUIM; ORTEGA, PABLO; ANDREU, TERESA; VOZ, CRISTOBAL; SAUCEDO, EDGARDO; MASCARO, LUCIA H.. The Influence of Annealing on the Sb Layer in the Synthesis of [001]-Oriented Sb₂Se₃ Film for Photoelectrochemical Hydrogen Gas Generation. ADVANCED FUNCTIONAL MATERIALS, v. N/A, p. 16-pg., 2025-04-17. (21/07727-0, 16/12681-0, 17/21365-8, 17/11986-5, 13/07296-2)

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DE OLIVEIRA, JOAO P. J.; ANTUNES, FABIO C.; DIAS, THIAGO; CESAR, REINALDO; SILVA, GUILHERME G.; HUNT, JULIAN; DOUBEK, GUSTAVO; ZANIN, HUDSON. Porous metal substrates for solid oxide fuel cells: Manufacturing techniques and future perspectives. CERAMICS INTERNATIONAL, v. 51, n. 9, p. 22-pg., 2025-04-01. (22/02235-4, 17/11986-5, 17/11958-1, 14/02163-7)

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BLASKIEVICZ, SIRLON F.; TEIXEIRA, IVO F.; MASCARO, LUCIA H.; CARTA, MARIOLINO; MCKEOWN, NEIL B.; ZHAO, YUANZHU; MARKEN, FRANK. Hydrogen-Mediated Photoelectrocatalysis with Nickel-Modified Poly(Heptazine Imides). ELECTROCATALYSIS, v. 15, n. 1, p. 10-pg., 2023-11-11. (14/50249-8, 17/11986-5, 20/14741-6)

PARMA, EDUARDO; NAGAO, RAPHAEL. Modulating Li-ion battery voltage oscillations in phase field simulations. JOURNAL OF ENERGY STORAGE, v. 73, p. 9-pg., 2023-10-16. (17/11986-5, 20/12632-5, 21/08868-6)

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DA SILVA, FRANCISCO M. C.; SZOSTAK, RODRIGO; GUAITA, MARIA G. D.; TEIXEIRA, VERONICA C.; NOGUEIRA, ANA F.; TOLENTINO, HELIO C. N.. X-ray dose effects and strategies to mitigate beam damage in metal halide perovskites under high brilliance X-ray photon sources. ENERGY MATERIALS, v. 4, n. 5, p. 15-pg., 2024-10-01. (21/01357-6, 17/11986-5)

MOREIRA, CASSIO MURILO RODRIGUES; VICENTINI, RAFAEL; VENANCIO, RAISSA; ZANIN, HUDSON; FRANCO, DEBORA VILELA; DE SOUSA, LINDOMAR GOMES; DA SILVA, LEONARDO MORAIS. Understanding intra-pore electrolyte resistances and distributed capacitances in carbon electrodes used in supercapacitors using a robust modeling process to separate the charge-storage occurring into macro-, meso-, and micro-pore structures. JOURNAL OF ENERGY STORAGE, v. 101, p. 16-pg., 2024-09-28. (18/20756-6, 17/11958-1, 17/11986-5, 14/02163-7)

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KALINKE, CRISTIANE; CRAPNELL, ROBERT D.; DE OLIVEIRA, PAULO R.; JANEGITZ, BRUNO C.; BONACIN, JULIANO A.; BANKS, CRAIG E.. How to Improve Sustainability in Fused Filament Fabrication (3D Printing) Research?. GLOBAL CHALLENGES, v. 8, n. 7, p. 13-pg., 2024-04-23. (19/00473-2, 13/22127-2, 21/07989-4, 17/21097-3, 17/11986-5)

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Filed patent(s) as a result of this research project